SDS of cas: 120-14-9. Authors Shi, CZ; Li, FS; Chen, YQ; Lin, SJ; Hao, EJ; Guo, ZW; Wosqa, UT; Zhang, DD; Shi, L in AMER CHEMICAL SOC published article about in [Shi, Caizhe; Li, Fusheng; Chen, Yuqing; Lin, Shuangjie; Guo, Zhuowen; Wosqa, Urwa Tul; Zhang, Dandan; Shi, Lei] Dalian Univ Technol, Zhang Dayu Sch Chem, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China; [Hao, Erjun; Shi, Lei] Henan Normal Univ, Henan Key Lab Organ Funct Mol & Drug Innovat, Key Lab Green Chem Media & React, Minist Educ,Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China in 2021.0, Cited 51.0. The Name is 3,4-Dimethoxybenzaldehyde. Through research, I have a further understanding and discovery of 120-14-9
The concept of umpolung reactivity of p-allylmetal complexes has been developed as a powerful method for the allylation of aldehydes. This paper describes the photocatalytic umpolung strategy for the synthesis of nucleophilic allylcobalt complexes through a single-electron-transfer (SET) process. This strategy enables the metallaphotoredox allylation of carbonyls with allyl acetate using organic N,N-diisopropylethylamine as the terminal reductant bypassing the use of a stoichiometric amount of metals. Ultraviolet-visible spectroscopy was used to monitor the redox changes of cobalt in the reaction.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles