《Phenothiazine core promoted charge transfer in conjugated microporous polymers for photocatalytic Ugi-type reaction and aerobic selenation of indoles》 was written by Zhang, Weijie; Li, Sizhe; Tang, Xiang; Tang, Juntao; Pan, Chunyue; Yu, Guipeng. Application In Synthesis of 5-Fluoro-1H-indole And the article was included in Applied Catalysis, B: Environmental in 2020. The article conveys some information:
Task-specific design and construction of conjugated microporous polymers (CMPs) for classic organic transformation is highly significant but challenging. Herein, we report strategy to promote charge transfer in CMPs using phenothiazine unit as a core and commonly used building blocks (carbazole/benzene) as the linker. Featuring by wide visible-light absorption, narrow optical bandgap, and facilitated charge transfer, phenothiazine-core CMPs exhibited superior photocatalytic performance towards Ugi-type reaction and aerobic selenation of indoles compared with those phenothiazine-free counterparts and commonly reported photocatalysts. Furthermore, the photocatalytic enhancement achieved in the designed CMPs system represents a substantial advance and verifies the viability of a simple strategy to tailor the photophys. properties of CMPs, which may facilitate the design of new photocatalysts.5-Fluoro-1H-indole(cas: 399-52-0Application In Synthesis of 5-Fluoro-1H-indole) was used in this study.
5-Fluoro-1H-indole(cas: 399-52-0) is a member of aromaticfluorinated building blocks. Depending on which substituents are present, fluoroaromatic intermediates can be converted into fluorinated or fluorine-free commercial end products.Fluorine-containing aromatics have been incorporated into drugs (hypnotics, tranquilizers, antiinflammatory agents, analgesics, antibacterials).Application In Synthesis of 5-Fluoro-1H-indole
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Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles