White, James D.’s team published research in Organic Letters in 8 | CAS: 167015-84-1

Organic Letters published new progress about 167015-84-1. 167015-84-1 belongs to indole-building-block, auxiliary class Indols, name is tert-Butyl 3-(2-aminoethyl)-1H-indole-1-carboxylate, and the molecular formula is C6H10O7, Quality Control of 167015-84-1.

White, James D. published the artcileTandem Photocycloaddition-Retro-Mannich Fragmentation of Enaminones. A Route to Spiropyrrolines and the Tetracyclic Core of Koumine, Quality Control of 167015-84-1, the publication is Organic Letters (2006), 8(6), 1081-1084, database is CAplus and MEDLINE.

Intramol. [2+2] photocycloaddition of β-aminoalkylidene malonates gives transiently a cyclobutane which undergoes retro-Mannich fragmentation to a Δ1-pyrroline. The tandem sequence, exemplified in two series based on tryptamine and aminoethyl-1,4-cyclohexadiene, leads to a spiroindolopyrroline skeleton (I) and to the nonindolenine portion (II) of koumine.

Organic Letters published new progress about 167015-84-1. 167015-84-1 belongs to indole-building-block, auxiliary class Indols, name is tert-Butyl 3-(2-aminoethyl)-1H-indole-1-carboxylate, and the molecular formula is C6H10O7, Quality Control of 167015-84-1.

Referemce:
https://www.nature.com/articles/s41429-020-0333-2,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles