Electron donor-acceptor complex-catalyzed photoredox reactions mediated by DIPEA and inorganic carbonates was written by Zhou, Qingli;Sun, Chenggang Guo;Liu, Xing;Li, Xiaofan;Shao, Ziyan;Tan, Kai;Shen, Yuehai. And the article was included in Organic Chemistry Frontiers in 2022.Recommanded Product: 1,3-Dioxoisoindolin-2-yl 2-phenoxyacetate This article mentions the following:
A catalytic EDA complex, composed of DIPEA as a donor catalyst, NHPI ester as the acceptor, and inorganic carbonate as a stabilizer and electron transfer mediator, is reported. This photoactivation system is a simple, efficient and sustainable radical generation platform for developing decarboxylative reactions of NHPI esters. Alkylated coumarins, phenanthridine derivatives and tertiary oxindoles were synthesized using this approach without need of metal complex or organic dye photocatalysts. In the experiment, the researchers used many compounds, for example, 1,3-Dioxoisoindolin-2-yl 2-phenoxyacetate (cas: 109524-10-9Recommanded Product: 1,3-Dioxoisoindolin-2-yl 2-phenoxyacetate).
1,3-Dioxoisoindolin-2-yl 2-phenoxyacetate (cas: 109524-10-9) belongs to indole derivatives. Indole could be stereoselectively alkylated with chiral cyclopentyl sulfone reagent. It is used in perfumery and in making tryptophan, an essential amino acid, and indoleacetic acid (heteroauxin), a hormone that promotes the development of roots in plant cuttings.Recommanded Product: 1,3-Dioxoisoindolin-2-yl 2-phenoxyacetate
Referemce:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles