An article Single C(sp(3))-F Bond Activation in a CF3 Group: Ipso-Defluorooxylation of (Trifluoromethyl)alkenes with Oximes WOS:000459366800060 published article about FUNCTIONALIZED GEM-DIFLUOROALKENES; FLUORINE ELIMINATION; 3+2 CYCLOADDITION; ALKYL FLUORIDES; H BONDS; HYDRODEFLUORINATION; SUBSTITUTION; CLEAVAGE; ALKENES; ACCESS in [Zeng, Hao; Zhu, Chuanle; Jiang, Huanfeng] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China in 2019.0, Cited 69.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Product Details of 100-51-6
The first defluorinative ipso-functionalization reaction of (trifluoromethyl)alkenes is reported. This exclusively regioselective ipso-defluorooxylation of (trifluoromethyl)alkenes with oximes affords various attractive O-(1,1-difluoroallyl)oxime ethers efficiently via a chemoselective single C(sp(3))-F bond activation in the CF3 group. Primary mechanism studies indicated an anionic S(N)2-type substitution pathway might be involved in this transformation.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles