In 2019.0 ORG LETT published article about ONE-POT SYNTHESIS; ACCEPTORLESS DEHYDROGENATION; BORROWING HYDROGEN; PINCER COMPLEXES; ALKYLATION; IRON; CATALYSTS; SECONDARY; COOPERATION; OLEFINATION in [Gawali, Suhas Shahaji; Pandia, Biplab Keshari; Gunanathan, Chidambaram] Natl Inst Sci Educ & Res, HBNI, Sch Chem Sci, Bhubaneswar 752050, India in 2019.0, Cited 60.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. SDS of cas: 100-51-6
A simple protocol of manganese catalyzed selective alpha-alkenylation of ketones using primary alcohols is reported. The reactions proceeded well with a low loading of catalyst (0.3 mol %). The overall transformation operates through O-H bond activation of primary alcohols via dearomatization-aromatization metal ligand cooperation in the catalyst to provide the corresponding aldehydes, which further undergo condensation with methylene ketones to deliver alpha,beta-unsaturated ketones. This selective alpha-alkenylation proceeds with the release of water and liberation of molecular hydrogen.
About Benzyl Alcohol, If you have any questions, you can contact Gawali, SS; Pandia, BK; Gunanathan, C or concate me.. SDS of cas: 100-51-6
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles