An article Toward hydrogen economy: Selective guaiacol hydrogenolysis under ambient hydrogen pressure WOS:000526110500045 published article about LIGNIN-DERIVED PHENOLS; MODEL-COMPOUND; HYDRODEOXYGENATION; CYCLOHEXANOL; CONVERSION; CATALYSTS; PD/C; DEPOLYMERIZATION; CLEAVAGE; METHANOL in [Zhou, Hui; Wang, Hsin; Sadow, Aaron D.; Slowing, Igor I.] US DOE, Ames Lab, Ames, IA 50011 USA; [Wang, Hsin; Sadow, Aaron D.; Slowing, Igor I.] Iowa State Univ, Dept Chem, Ames, IA 50011 USA in 2020.0, Cited 42.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Safety of m-Methoxyphenol
The conversion of guaiacol into the nylon precursors, cyclohexanol and cyclohexanone, is catalyzed by palladium supported on high surface area ceria (Pd/HS CeO2) under mild conditions (100 degrees C, <= 1 bar H-2) via sequential hydrodemethoxylation and hydrogenation. In contrast, the 2-methoxycyclohexanol side product is generated by direct guaiacol hydrogenation. Reaction selectivity is determined by competing CeO bond hydrogenolysis versus arene hydrogenation. Hydrogenolysis selectivity increases as H-2 pressure decreases, and over 80 % H-2 is incorporated into the products at 1 bar H-2. Higher reactivity of guaiacol than anisole implies that the hydroxyl group is essential in Pd/HS CeO2 catalysis. Participation of water in the conversion is evidenced by deuterium incorporation at non-exchangeable positions when the reaction is performed in D2O. The combination of near quantitative mass balance of H-2, high recyclability, and use of water as a solvent offers a simple, green and efficient conversion of lignin-derived aromatics into commercial products. Safety of m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Zhou, H; Wang, H; Sadow, AD; Slowing, II or concate me.
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