An article Solid Base Bi24O31Br10(OH) with Active Lattice Oxygen for the Efficient Photo-Oxidation of Primary Alcohols to Aldehydes WOS:000471976400020 published article about SELECTIVE OXIDATION; VISIBLE-LIGHT; BENZYL ALCOHOL; PHOTOCATALYTIC ACTIVITY; AEROBIC OXIDATION; CATALYSTS; GLYCEROL; NANOPARTICLES; PD; DEHYDROGENATION in [Dai, Yitao; Ren, Pengju; Li, Yaru; Shen, Yanbin; Li, Yongwang; Niemantsverdriet, Hans; Xiang, Hongwei; Wen, Xiaodong; Su, Ren] Synfuels China Technol Co Ltd, SynCat Beijing, Leyuan South St 2,1 Yanqi Econ Dev Zone C, Beijing 101407, Peoples R China; [Dai, Yitao; Besenbacher, Flemming; Lock, Nina] Aarhus Univ, Interdisciplinary Nanosci Ctr iNANO, Gustav Wieds Vej 14, DK-8000 Aarhus C, Denmark; [Hao, Weichang] Beihang Univ, Dept Phys, Ctr Mat Phys & Chem, Beijing 100191, Peoples R China; [Lv, Dongdong; Niemantsverdriet, Hans] Syngaschem BV, SynCat DIFFER, NL-6336 HH Eindhoven, Netherlands; [Li, Yaru; Xiang, Hongwei; Wen, Xiaodong; Lewis, James P.] Chinese Acad Sci, Inst Coal Chem, State Key Lab Coal Convers, Taiyuan 030001, Shanxi, Peoples R China; [Lewis, James P.] West Virginia Univ, Dept Phys & Astron, Morgantown, WV 26506 USA in 2019.0, Cited 60.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. HPLC of Formula: C7H8O
The selective oxidation of primary alcohols to aldehydes by O-2 instead of stoichiometric oxidants (for example, Mn-VII, Cr-VI, and Os-IV) is an important but challenging process. Most heterogeneous catalytic systems (thermal and photocatalysis) require noble metals or harsh reaction conditions. Here we show that the Bi24O31Br10(OH) photocatalyst is very efficient in the selective oxidation of a series of aliphatic (carbon chain from C-1 to C-10) and aromatic alcohols to their corresponding aldehydes/ketones under visible-light irradiation in air at room temperature, which would be challenging for conventional thermal and light-driven processes. High quantum efficiencies (71% and 55% under 410 and 450nm irradiation) are reached in a representative reaction, the oxidation of isopropanol. We propose that the outstanding performance of the Bi24O31Br10(OH) photocatalyst is associated with basic surface sites and active lattice oxygen that boost the dehydrogenation step in the photo-oxidation of alcohols.
HPLC of Formula: C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Dai, YT; Ren, PJ; Li, YR; Lv, DD; Shen, YB; Li, YW; Niemantsverdriet, H; Besenbacher, F; Xiang, HW; Hao, WC; Lock, N; Wen, XD; Lewis, JP; Su, R or concate me.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles