An article Organogermanium(II) Hydrides as a Source of Highly Soluble LiH WOS:000528860600001 published article about MAIN-GROUP ELEMENTS; BOND COVALENT RADII; UNACTIVATED ALKENES; SINGLE-BOND; BASIS-SETS; H BONDS; ACTIVATION; GERMANIUM(II); STATE; CHEMISTRY in [Tremmel, Jakub; Dostal, Libor; Ruzicka, Ales; Jambor, Roman] Univ Pardubice, Dept Gen & Inorgan Chem, Pardubice 53210, Czech Republic; [Tydlitat, Jiri] Univ Pardubice, Inst Organ Chem & Technol, Pardubice 53210, Czech Republic; [Deraet, Xavier; Turek, Jan] Vrije Univ Brussel, Eenheid Algemene Chem ALGC, Pl Laan 2, B-1050 Brussels, Belgium in 2020.0, Cited 76.0. Name: Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
The reactions of monomeric C,N-chelated organogermanium(II) hydride L(H)Ge.BH3 with organolithium salts RLi yielded lithium hydrogermanatoborates (Li(THF)(2){BH3[L(H)GeR]})(2). Compound (Li(THF)(2){BH3[L(H)GePh]})(2) was used as a source of LiH for the reduction of organic C=O or C=N bonds in nonpolar solvents accompanied by the elimination of a neutral complex L(Ph)Ge.BH3. The interaction of (Li(THF)(2){BH3[L(H)GePh]})(2) with the polar C=O bond was further investigated by computational studies revealing a plausible geometry of a pre-reactive intermediate. The experimental and theoretical studies suggest that, although the Li atom of (Li(THF)(2){BH3[L(H)GePh]})(2) coordinates the C=O bond, the GeH fragment is the active species in the reduction reaction. Finally, benzaldehyde was reduced by a mixture of L(H)Ge.BH3 with PhLi in nonpolar solvents.
Name: Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Tremmel, J; Tydlitat, J; Dostal, L; Ruzicka, A; Deraet, X; Turek, J; Jambor, R or concate me.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles