Name: Benzyl Alcohol. In 2019.0 ACS CATAL published article about ALLYLIC ALCOHOLS; ENANTIOSELECTIVE SYNTHESIS; ALPHA-IODOKETONES; ISOMERIZATION; SHIFT/CHLORINATION; CASCADE; KETONES; CORE; ACID; ARYL in [Molleti, Nagaraju; Martinez-Erro, Samuel; Carretero Cerdan, Alba; Sanz-Marco, Amparo; Martin-Matute, Belen] Stockholm Univ, Dept Organ Chem, SE-10691 Stockholm, Sweden; [Carretero Cerdan, Alba; Gomez-Bengoa, Enrique] Univ Basque Country, Dept Organ Chem 1, UPV EHU, San Sebastin 20080, Spain in 2019.0, Cited 56.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
The isomerization of dienyl alcohols and polyenyl alkyl ethers catalyzed by TBD (1,5,7-triazabicyclo[4.4.0]dec-5-ene) under metal-free conditions is presented. Two reaction pathways have been observed. For dienyl alcohols, the reaction proceeds by a [1,3]-proton shift to give gamma,delta-unsaturated ketones exclusively. On the other hand, the reaction with polyenyl alkyl ethers gives the corresponding conjugated vinyl ethers in good yields (up to 85%), with regioselectivities up to >20:1. Experimental and computational investigations suggest that the mechanism proceeds through consecutive chain-walking proton shifts (base walk) mediated by TBD.
Name: Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Molleti, N; Martinez-Erro, S; Cerdan, AC; Sanz-Marco, A; Gomez-Bengoa, E; Martin-Matute, B or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles