Recently I am researching about HOMOGENEOUS CATALYTIC-HYDROGENATION; CARBOXYLIC-ACID ESTERS; ASYMMETRIC HYDROGENATION; EFFICIENT HYDROGENATION; BIFUNCTIONAL ADDITION; RUTHENIUM COMPLEXES; ALCOHOLS; AMIDES; KETONES; BASE, Saw an article supported by the Natural Sciences and Engineering Research Council of Canada (NSERC)Natural Sciences and Engineering Research Council of Canada (NSERC); University of AlbertaUniversity of Alberta; Marshall Syska Chemistry Graduate Scholarship. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Endean, RT; Rasu, L; Bergens, SH. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol. Product Details of 150-19-6
The catalyst system trans-Ru(H)(2)(1R,2R)-N,N-bis{2-[bis (3,-dimethylphenyl)phosphino]benzyl}cyclohexane-1,2-diamine, NaOEt, in DME or THF solvent hydrogenates a series of functionalized racemic esters under mild conditions with dynamic kinetic resolution with up to 100% conversion, 95% enantiomeric excess, and 1000 turnovers. A preliminary mechanistic study reveals that several exchange and scrambling processes occur during the hydrogenation.
Product Details of 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Endean, RT; Rasu, L; Bergens, SH or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles