SDS of cas: 123-11-5. Recently I am researching about MEDIATED ALDOL REACTION; ENANTIOSELECTIVE SYNTHESIS; STEREOSELECTIVE-SYNTHESIS; ESTERS; POTENT; DICYCLOHEXYLIODOBORANE; ISOFLAVONOIDS; INHIBITORS, Saw an article supported by the Southeastern Louisiana University; Louisiana Biomedical Research Network (LBRN). Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Thomas, AY; Walls, TL; Nelson, BN; Primeaux, SW; Chanda, PB. The CAS is 123-11-5. Through research, I have a further understanding and discovery of 4-Methoxybenzaldehyde
In contrast to methyl phenylacetates, methyl arylacetates do not provide syn-aldols in the dicyclohexylboron triflate/triethylamine (Chx(2)BOTf/Et3N)-mediated enolboration-aldolization reaction. However, a combination of a less bulky boron reagent (dibutylboron triflate, n-Bu2BOTf), a bulky amine (i-Pr2NEt, and ambient temperature is required to obtain syn-aldols from methyl arylacetates. The corresponding anti-aldol products have been synthesized by the enolboration-aldolization of methyl arylacetates in the presence of Chx(2)BOTf/Et3N at a lower temperature. We report the first example of a complementary syn- and anti-selective enolboration-aldolization of arylacetates.
SDS of cas: 123-11-5. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Thomas, AY; Walls, TL; Nelson, BN; Primeaux, SW; Chanda, PB or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles