In 2019.0 J AM CHEM SOC published article about NON-INNOCENT LIGANDS; ASYMMETRIC HYDROGENATION; MILD REDUCTION; ACTIVE LIGANDS; HYDROBORATION; AMIDES; DERIVATIVES; REACTIVITY; CARBONYL; TERPYRIDINE in [Zhang, Guoqi; Wu, Jing] CUNY, Grad Ctr, Dept Sci, John Jay Coll, New York, NY 10019 USA; [Zhang, Guoqi; Wu, Jing] CUNY, Grad Ctr, PhD Chem Program, New York, NY 10019 USA; [Wu, Jing; Zheng, Shengping; Neary, Michelle C.] CUNY, Dept Chem, Hunter Coll, New York, NY 10065 USA; [Mao, Jincheng] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu, Sichuan, Peoples R China; [Flores, Marco; Trovitch, Ryan J.] Arizona State Univ, Sch Mol Sci, Tempe, AZ 85287 USA; [Dub, Pavel A.] Los Alamos Natl Lab, Chem Div, Los Alamos, NM 87545 USA in 2019.0, Cited 61.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Product Details of 100-51-6
Catalysis is the second largest application for V after its use as an additive to improve steel production. Molecular complexes of vanadium(V) are particularly useful and efficient catalysts for oxidation processes; however, their ability to catalyze reductive transformations has yet to be fully explored. Here we report the first examples of polar organic functionality reduction mediated by V. Open-shell V-III complexes that feature a pi-radical monoanionic 2,2′:6′,2 ”-terpyridine ligand (Rtpy(center dot))(-) functionalized at the 4′-position (R = (CH3)(3)SiCH2, C6H5) catalyze mild and chemoselective hydroboration and hydrosilylation of functionalized ketones, aldehydes, imines, esters, and carboxamides with turnover numbers (TONs) of up to similar to 1000 and turnover frequencies (TOFs) of up to similar to 500 h(-1).Computational evaluation of the precatalyst synthesis and activation has revealed underappreciated complexity associated with the redox-active tpy chelate.
About Benzyl Alcohol, If you have any questions, you can contact Zhang, GQ; Wu, J; Zheng, SP; Neary, MC; Mao, JC; Flores, M; Trovitch, RJ; Dub, PA or concate me.. Product Details of 100-51-6
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles