Recently I am researching about ARYL-ALPHA-DIAZOACETATES; PROPARGYL REARRANGEMENT; INDUSTRIAL PERSPECTIVE; ORTHO-ARYLATION; COUNTER ANIONS; HYDROPHENOXYLATION; CYCLIZATION; ALKYNES; ACTIVATION; B(C6F5)(3), Saw an article supported by the DAADDeutscher Akademischer Austausch Dienst (DAAD)European Commission. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Adak, T; Schulmeister, J; Dietl, MC; Rudolph, M; Rominger, F; Hashmi, ASK. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol. Formula: C7H8O2
A highly chemo- and stereoselective addition of unprotected phenols to haloalkynes was developed. A ligand and counterion controlled process enabled the highly site-selective and chemoselective C-H bond functionalization of phenol derivatives with haloalkynes in moderate to excellent yield at room temperature. The simple availability of the starting materials in combination with the preferred para-C-H functionalization over a competing O-H insertion makes this an attractive protocol. The stereoselectivity of the products depends on the choice of the catalyst. From a synthetic prospective, this method offers an efficient route towards vinyl chlorides, which are valuable precursors for the synthesis of pharmaceutical drugs.
About m-Methoxyphenol, If you have any questions, you can contact Adak, T; Schulmeister, J; Dietl, MC; Rudolph, M; Rominger, F; Hashmi, ASK or concate me.. Name: m-Methoxyphenol
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles