An article Cyclometalated Ruthenium Pincer Complexes as Catalysts for the alpha-Alkylation of Ketones with Alcohols WOS:000531606100017 published article about HYDROGEN-TRANSFER REDUCTION; H BOND ACTIVATION; BORROWING HYDROGEN; ACCEPTORLESS DEHYDROGENATION; METHANOL DEHYDROGENATION; CO2 HYDROGENATION; OS COMPLEXES; RU; PNP; AUTOTRANSFER in [Piehl, Patrick; Amuso, Roberta; Alberico, Elisabetta; Junge, Henrik; Neumann, Helfried; Beller, Matthias] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany; [Amuso, Roberta; Gabriele, Bartolo] Univ Calabria, Dept Chem & Chem Technol, Lab Ind & Synthet Organ Chem LISOC, Via Pietro Bucci 12-C, I-87036 Arcavacata Di Rende, CS, Italy; [Alberico, Elisabetta] CNR, Ist Chim Biomol, Tr La Crucca 3, I-07100 Sassari, Italy in 2020, Cited 94. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Computed Properties of C7H8O
Ruthenium PNP pincer complexes bearing supplementary cyclometalated C,N-bound ligands have been prepared and fully characterized for the first time. By replacing CO and H- as ancillary ligands in such complexes, additional electronic and steric modifications of this topical class of catalysts are possible. The advantages of the new catalysts are demonstrated in the general alpha-alkylation of ketones with alcohols following a hydrogen autotransfer protocol. Herein, various aliphatic and benzylic alcohols were applied as green alkylating agents for ketones bearing aromatic, heteroaromatic or aliphatic substituents as well as cyclic ones. Mechanistic investigations revealed that during catalysis, Ru carboxylate complexes are predominantly formed whereas neither the PNP nor the CN ligand are released from the catalyst in significant amounts.
Computed Properties of C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Piehl, P; Amuso, R; Alberico, E; Junge, H; Gabriele, B; Neumann, H; Beller, M or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles