Recommanded Product: 99-93-4. In 2019.0 CHEM SCI published article about CATALYZED INTERMOLECULAR TRIFLUOROMETHYLARYLATION; C-H BONDS; PHOTOREDOX CATALYSIS; UNACTIVATED ALKENES; FLUOROALKYLATION REACTIONS; DIRECT ARYLATION; ACID ANHYDRIDES; B BOND; PYRIDINE; ACTIVATION in [Cao, Jia; Wang, Guoqiang; Gao, Liuzhou; Chen, Hui; Liu, Xueting; Li, Shuhua] Nanjing Univ, Sch Chem & Chem Engn, Inst Theoret & Computat Chem, Key Lab Mesoscop Chem,Minist Educ, Nanjing 210093, Jiangsu, Peoples R China; [Cheng, Xu] Nanjing Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Adv Organ Mat, Inst Chem & Biomed Sci, Nanjing 210093, Jiangsu, Peoples R China; [Cao, Jia] Yanan Univ, Sch Chem & Chem Engn, Shaanxi Key Lab Chem React Engn, Yanan 716000, Peoples R China in 2019.0, Cited 102.0. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4.
A metal-free and photo-free method for the perfluoroalkylative pyridylation of alkenes has been developed via a combination of computational and experimental studies. Density functional theory calculations and control experiments indicate that the homolysis of R-f X (X 1/4 Br, I) bonds by the 4-cyanopyridine-boryl radicals in situ generated from 4-cyanopyridine and B(2)pin(2) is the key step. Sequential addition of Rf radicals to alkenes and the selective cross-coupling of the resulting alkyl radicals and 4-cyanopyridineboryl radicals gives alkene difunctionalization products with a quaternary carbon center. This method exhibits a broad substrate scope and good functional group compatibility.
Recommanded Product: 99-93-4. About 4′-Hydroxyacetophenone, If you have any questions, you can contact Cao, J; Wang, GQ; Gao, LZ; Chen, H; Liu, XT; Cheng, X; Li, SH or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles