Rodriguez, RI; Mollari, L; Aleman, J in [Rodriguez, Ricardo I.; Mollari, Leonardo; Aleman, Jose] Univ Autonoma Madrid, Dept Organ Chem, Modulo 1, Madrid 28049, Spain published Light-Driven Enantioselective Synthesis of Pyrroline Derivatives by a Radical/Polar Cascade Reaction in 2021.0, Cited 61.0. SDS of cas: 123-11-5. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5.
Herein, a light-driven, atom-economical process that provides access to enantiomerically enriched substituted chiral 1-pyrroline derivatives is introduced. The strategy involves the distal functionalization of acyl heterocycles through a hydrogen-atom transfer (HAT) process and the use of tailor-made ketimines as reliable electrophilic partners. This transformation is translated into an enantiomerically controlled radical/polar cascade reaction in which water is produced as the sole by-product and stereoselectivity is dictated by coordination to a chiral-at-rhodium catalyst.
About 4-Methoxybenzaldehyde, If you have any questions, you can contact Rodriguez, RI; Mollari, L; Aleman, J or concate me.. SDS of cas: 123-11-5
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles