Authors Poshala, S; Thunga, S; Golla, S; Satheesh, V; Kokatla, HP in WILEY-V C H VERLAG GMBH published article about ENANTIOSELECTIVE SYNTHESIS; TRICHLOROMETHYL KETONES; CARBOXYLIC-ACIDS; TRICHLOROACETATE; REARRANGEMENT in [Poshala, Soumya; Thunga, Sanjeeva; Golla, Sivaparwathi; Satheesh, Vanaparthi; Kokatla, Hari Prasad] Natl Inst Technol Warangal, Dept Chem, Warangal 506004, Telangana, India in 2019.0, Cited 38.0. Safety of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
A novel one-pot approach for the synthesis of trichloroacetates is described. Use of inexpensive, commercially available trichloroacetonitrile as a trichloroacyl source has made this protocol have more industrial applications. This one-pot approach is applicable to a wide range of alcohols as demonstrated by 28 examples with good to excellent yields in the order of 93%. Trichloroacetates were characterized by infrared, NMR spectra and further the structure of 2-(1,3-dioxoisoindolin-2-yl)ethyl-2,2,2-trichloroacetate was confirmed by single-crystal X-ray diffraction. Moreover, benzyl trichloroacetates synthesized were converted into corresponding benzyl iodides in good yields (51-70%). In addition, bypassing harsh reagents, use of cheaper, commercially available sodium iodide as nucleophile and mild reaction conditions are some of practical features of this methodology.
Safety of Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Poshala, S; Thunga, S; Golla, S; Satheesh, V; Kokatla, HP or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles