Bernauer, J; Wu, GJ; Jacobi von Wangelin, A in [Bernauer, Josef; Wu, Guojiao; Jacobi von Wangelin, Axel] Univ Hamburg, Dept Chem, Martin Luther King Pl 6, D-20146 Hamburg, Germany published Iron-catalysed allylation-hydrogenation sequences as masked alkyl-alkyl cross-couplings in 2019, Cited 58. Recommanded Product: (E)-2-Methylbut-2-enoic acid. The Name is (E)-2-Methylbut-2-enoic acid. Through research, I have a further understanding and discovery of 80-59-1.
An iron-catalysed allylation of organomagnesium reagents (alkyl, aryl) with simple allyl acetates proceeds under mild conditions (Fe(OAc)(2) or Fe(acac)(2), Et2O, r.t.) to furnish various alkene and styrene derivatives. Mechanistic studies indicate the operation of a homotopic catalyst. The sequential combination of such iron-catalysed allylation with an iron-catalysed hydrogenation results in overall C(sp(3))-C(sp(3))-bond formation that constitutes an attractive alternative to challenging direct cross-coupling protocols with alkyl halides.
Recommanded Product: (E)-2-Methylbut-2-enoic acid. About (E)-2-Methylbut-2-enoic acid, If you have any questions, you can contact Bernauer, J; Wu, GJ; Jacobi von Wangelin, A or concate me.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles