Recently I am researching about C-H FUNCTIONALIZATION; N-TOSYLHYDRAZONES; STEREOSELECTIVE FUNCTIONALIZATION; QUATERNARY STEREOCENTERS; ASYMMETRIC-SYNTHESIS; CONSTRUCTION; VINYLDIAZOMETHANES; REAGENTS; ESTERS; ARYL, Saw an article supported by the Knut and Alice Wallenberg FoundationKnut & Alice Wallenberg Foundation [KAW2016.0153]; European Research CouncilEuropean Research Council (ERC)European Commission [714737]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Yu, ZZ; Mendoza, A. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol. Quality Control of Benzyl Alcohol
The enantioselective assembly of quaternary stereocenters through sequential functionalization of versatile carbon-atom precursors has the potential to systematize the synthesis of these ubiquitous stereogenic elements. Herein, we report two catalytic processes that allow the realization of this concept in the enantioselective synthesis of cyclopropanes. We demonstrate that C-H functionalization, carbene-transfer, and decarboxylative cross-coupling can sequentially take place in the same carbon atom to obtain highly enantioenriched cyclopropane products. The reactions reported herein give access to redox-active analogues of privileged aryldiazoacetates and demonstrate their enantioselective carbene transfer with a simple and practical rhodium catalyst.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles