Safety of m-Methoxyphenol. Zaitceva, O; Beneteau, V; Ryabukhin, DS; Eliseev, II; Kinzhalov, MA; Louis, B; Vasilyev, AV; Pale, P in [Zaitceva, Olesia; Beneteau, Valerie; Louis, Benoit; Pale, Patrick] Univ Strasbourg, Inst Chim, UMR 7177, CNRS, 4 Rue B Pascal, F-67000 Strasbourg, France; [Eliseev, Ivan I.; Kinzhalov, Mikhal A.; Vasilyev, Aleksander V.] St Petersburg State Univ, 7-9 Univ Skaya Nab, St Petersburg 199034, Russia; [Zaitceva, Olesia; Ryabukhin, Dmitry S.; Vasilyev, Aleksander V.] St Petersburg State Forest Tech Univ, 5 Inst Skii Per, St Petersburg 194021, Russia; [Louis, Benoit] Univ Strasbourg, Inst Chim & Proc Energie Environm & Sante, ECPM, 25 Rue Becquerel, F-67087 Strasbourg 2, France published Cyclization of aryl 3-aryl propynoates into 4-arylcoumarins catalyzed by cyclometalated Platinum(II) complexes in 2020.0, Cited 66.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.
Cyclometalated (ppy)Pt-II complexes (ppy = 2-phenylpyridinato-C-2,N) catalyze the intramolecular cyclization of aryl propynoates to form coumarins and benzocoumarins. The complex [(ppy)PtCl(MeCN)] (5 mol %) was the most active and efficient catalyst for such reaction, especially in the presence of AgSbF6 (15 mol %) in 1,2-dichloroethane. With this catalytic system, a wide range of substituents and functional groups proved compatible with the cyclization process, leading to a large variety of substituted coumarins and benzocoumarins (22 examples, 77-99%) (C) 2020 Elsevier Ltd. All rights reserved.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles