Name: 4-Methoxybenzaldehyde. Zhao, FH; Singh, TSN; Xiao, YM; Su, WC; Yang, DY; Jia, CQ; Li, JQ; Qin, ZH in [Zhao, Fenghai; Xiao, Yumei; Su, Wangcang; Yang, Dongyan; Jia, Changqing; Li, Jia-Qi; Qin, Zhaohai] China Agr Univ, Dept Chem, Coll Sci, Innovat Ctr Pesticide Res, Beijing 100193, Peoples R China; [Singh, Thishana] Univ KwaZulu Natal, Coll Agr Engn & Sci, Sch Chem & Phys, ZA-4000 Durban, South Africa; [Su, Wangcang] Henan Acad Agr Sci, Inst Plant Protect, Zhengzhou 450002, Peoples R China; [Yang, Dongyan] Zhongkai Univ Agr & Engn, Coll Chem & Chem Engn, Guangzhou 510225, Guangdong, Peoples R China; [Jia, Changqing] Tongren Polytech Coll, Natl Engn Res Ctr, Tongren 554300, Guizhou, Peoples R China published Divergent Synthesis of Substituted Amino-1,2,4-triazole Derivatives in 2021.0, Cited 23.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5.
A divergent efficient assembly of disubstituted 1,2,4-triazoles was established by cyclization of readily accessible N’-nitro-2-hydrocarbylidene-hydrazinecarboximidamides with moderate to excellent yields under mild reaction conditions. This divergent synthetic strategy was achieved simply by varying the reaction conditions. Under acidic conditions, amino-1,2,4-triazoles were obtained by an intramolecular redox reaction involving the NO2 group. Control experiments and DFT studies revealed that this transformation proceeds via an intramolecular 1,3-hydride transfer pathway leading to HNO2 elimination. Under neutral conditions with water as the solvent, nitroimino-1,2,4-triazoles were obtained by oxidative intramolecular annulation under air.
Name: 4-Methoxybenzaldehyde. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Zhao, FH; Singh, TSN; Xiao, YM; Su, WC; Yang, DY; Jia, CQ; Li, JQ; Qin, ZH or concate me.
Reference:
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles