Authors Chen, J; Yang, HL; Fu, HQ; He, HY; Zeng, Q; Li, XH in ROYAL SOC CHEMISTRY published article about BOND-CLEAVAGE; PHOTOCATALYTIC OXIDATION; CATALYTIC-OXIDATION; AEROBIC OXIDATION; VISIBLE-LIGHT; PB/PBO2 ANODE; DEGRADATION; DEPOLYMERIZATION; HYDROGENOLYSIS; COPPER in [Chen, Jing; Yang, Hanling; Fu, Hongquan; Zeng, Qiang; Li, Xuehui] South China Univ Technol, Sch Chem & Chem Engn, State Key Lab Pulp & Paper Engn, Guangzhou 510640, Peoples R China; [He, Hongyan] Chinese Acad Sci, CAS Key Lab Green Proc & Engn, Inst Proc Engn, Beijing 100190, Peoples R China in 2020.0, Cited 67.0. Product Details of 99-93-4. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4
Electrochemical oxidation is a promising and effective method for lignin depolymerization owing to its selective oxidation capacity and environmental friendliness. Herein, the electrooxidation of non-phenolic alkyl aryl ether monomers and beta-O-4 dimers was experimentally (by cyclic voltammetry, in situ spectroelectrochemistry, and gas chromatography-mass spectroscopy) and theoretically (by DFT calculations) explored in detail. Compared to the reported literature (T. Shiraishi, T. Takano, H. Kamitakahara and F. Nakatsubo, Holzforschung, 2012, 66(3), 303-309), 1-(4-ethoxyphenyl)ethanol showed a distinguishable oxidation pathway, where the resulting carbonyl product surprisingly underwent a bond cleavage on alkyl-aryl ether to ultimately produce a quinoid like compound. In contrast, beta-O-4 dimers, like 2-phenoxy-1-phenethanol and 2-phenoxyacetophenone also demonstrated electrochemical oxidation induced by C-beta-O and C-alpha-C-beta bond cleavages. For the oxidation products, the presence of the C-alpha-hydroxyl group in dimers was the key to selectively generate aldehyde-containing species under mild electrochemical conditions, otherwise it produces alcohol-containing products following a different mechanism compared to the C-alpha = O containing dimers.
Product Details of 99-93-4. Welcome to talk about 99-93-4, If you have any questions, you can contact Chen, J; Yang, HL; Fu, HQ; He, HY; Zeng, Q; Li, XH or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles