Safety of Benzyl Alcohol. Authors Akinnawo, CA; Bingwa, N; Meijboom, R in ROYAL SOC CHEMISTRY published article about in [Akinnawo, Christianah Aarinola; Bingwa, Ndzondelelo; Meijboom, Reinout] Univ Johannesburg, Dept Chem Sci, Res Ctr Synth & Catalysis, POB 524, ZA-2006 Johannesburg, South Africa in 2021.0, Cited 64.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Meerwein-Ponndorf-Verley reduction (MPVr) is a sustainable route for the chemoselective transformation of alpha,beta-unsaturated aldehydes. However, tailoring ZrO2 catalysts for improved surface-active sites and maximum performance in the MPV reaction is still a challenge. Here, we synthesized mesoporous zirconia (ZrO2) and metal-doped zirconia (M_ZrO2, M = Cr, Mn, Fe, and Ni). The incorporation of metal dopants into zirconia’s crystal framework alters its physico-chemical properties such as surface area and total acidity-basicity. The prepared catalysts were evaluated in the MPVr using 2-propanol as a hydrogen donor under mild reaction conditions. The catalysts’ remarkable reactivity depends mainly on their surface mesostructure’s intrinsic properties rather than the specific surface area. Cr_ZrO2, which is stable and sustainable, presented superior activity and 100% selectivity to unsaturated alcohols. The synergistic effect between Cr and Zr species in the binary oxide facilitated the Lewis acidity-induced performance of the Cr_ZrO2 catalyst. Our work presents the first innovative application of a well-designed mesoporous Cr_ZrO2 in the green synthesis of unsaturated alcohols with exceptional reactivity.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles