Category: indole-building-block. Huang, C; Gu, XY; Su, XY; Xu, ZC; Liu, R; Zhu, HJ in [Huang, Cheng; Gu, Xiangyu; Liu, Rui; Zhu, Hongjun] Nanjing Tech Univ, Sch Chem & Mol Engn, Nanjing 211816, Peoples R China; [Huang, Cheng; Su, Xiaoyan] Southeast Univ, ChengXian Coll, Dept Chem & Pharmaceut Engn, Nanjing, Peoples R China; [Xu, Zengchuang] Chinese Acad Sci, Shanghai Inst Tech Phys, Shanghai 200083, Peoples R China published Controllable synthesis of Co-MOF-74 catalysts and their application in catalytic oxidation of toluene in 2020, Cited 35. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
The morphology and size of Co-MOF-74 were effectively controlled by adjusting the water portion in DMF-H2O mixed solvent system, and six different Co-MOF-74 samples were successfully obtained. The water content can alter the deprotonation rate of the organic ligand and then change the nucleation rate of crystal, thus regulate morphology and size of Co-MOF-74. The discrepancy of morphology and size has significant effect on texture structure of Co-MOF-74 but without changing their composition. The formation mechanism of crystal growth was proposed by studying the change of reaction solution pH value. These samples exhibit morphology and size dependent catalytic activity in toluene oxidation. The flower-like sample has the best catalytic performance with 12.1% toluene conversion and 63.8% benzaldehyde selectivity. Additionally, the influence of reaction parameters on the catalytic oxidation reaction was also examined. Rearserch on the structure-property relationship of catalyst would be useful for rationally synthesizing novel MOF in heterogeneous catalysis.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles