Qiao, JY; Jiang, HS; Liu, XC; Xu, CZ; Sun, ZZ; Chu, WY in [Qiao, Jingyi; Jiang, Hongshuo; Liu, Xiaochong; Xu, Chunzhao; Sun, Zhizhong; Chu, Wenyi] Heilongjiang Univ, Coll Chem & Mat Sci, Harbin 150080, Heilongjiang, Peoples R China; [Qiao, Jingyi; Jiang, Hongshuo; Liu, Xiaochong; Xu, Chunzhao; Sun, Zhizhong; Chu, Wenyi] Heilongjiang Univ, Coll Chem & Mat Sci, Key Lab Chem Engn Proc & Technol High Efficiency, Harbin 150080, Heilongjiang, Peoples R China published Ruthenium-Catalyzed Synthesis of Quinazolinones through Hydrogen Transfer and Cyclization in 2019.0, Cited 43.0. Quality Control of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
An efficient ruthenium-catalyzed tandem cyclization for the formation of C-N bond was developed by using hydrogen transfer reaction and intramolecular cyclization. This process relied on the efficient availability of nitroarenes and primary alcohols to form C-N bond by hydrogen transfer reaction. This method could be widely used in the synthesis of quinazolinone skeletons due to less waste, higher reaction efficiency and better functional groups tolerance. A series of quinazolin-4(3H)-ones derivatives were obtained with high production by using nitroarenes and primary alcohols as the substrates. Finally, based on the experimental results, a reasonable series reaction mechanism was proposed.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles