Chang, XH; Zhang, QL; Guo, C in [Chang, Xihao; Zhang, Qinglin; Guo, Chang] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Anhui, Peoples R China published Electrochemical Reductive Smiles Rearrangement for C-N Bond Formation in 2019, Cited 77. SDS of cas: 98-17-9. The Name is 3-(Trifluoromethyl)phenol. Through research, I have a further understanding and discovery of 98-17-9.
A conceptually new and synthetically valuable radical Smiles rearrangement reaction is reported under undivided electrolytic conditions. This protocol employs an entirely new strategy for the electrochemical radical Smiles rearrangement. Remarkably, an amidyl radical generated from the cleavage of the N-O bond under reductive electrolytic conditions plays a crucial role in this transformation. Various hydroxylamine derivatives bearing different substituents are suitable in this electrochemical transformation, furnishing the corresponding amides in up to 86% yield.
SDS of cas: 98-17-9. Welcome to talk about 98-17-9, If you have any questions, you can contact Chang, XH; Zhang, QL; Guo, C or send Email.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles