COA of Formula: C8H8O2. Hauenschild, T; Hinderberger, D in [Hauenschild, Till; Hinderberger, Dariush] Martin Luther Univ Halle Wittenberg, Inst Chem, Phys Chem Complex Self Organizing Syst, Von Danckelmann Pl 4, D-06120 Halle, Saale, Germany published A Platform of Phenol-Based Nitroxide Radicals as an EPR Toolbox in Supramolecular and Click Chemistry in 2019, Cited 45. The Name is 4′-Hydroxyacetophenone. Through research, I have a further understanding and discovery of 99-93-4.
A large number (63) of well-defined nitroxide radicals, all phenol-based TEMPO and PROXYL esters, were synthesized using different strategies based on well-established Steglich esterifications. All of these radicals can be used as spin probes (SPs) and spin labels (SLs) for electron paramagnetic resonance (EPR) spectroscopy of supramolecular systems. Depending on the nature of the functional group(s) on each SP/SL, the synthesized nitroxide radicals serve as polyphilic molecular toolbox for the EPR-spectroscopic detection and characterization of specific types of interactions, e. g. pi-pi interactions, sulfur-sulfur interactions, hydrogen bonding, electrostatic and dipole-dipole interactions, and van der Waals and hydrophobic interactions, in the presence of the selected supramolecular systems of interest (e. g. proteins, peptides). For each synthesized SP/SL the water solubility was gravimetrically determined for use in aqueous solution at pH 7.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles