Quality Control of 4-Methoxybenzaldehyde. Authors Marcantonio, E; Curti, C; Battistini, L; Sartori, A; Cardinale, L; Pelosi, G; Zanardi, F in WILEY-V C H VERLAG GMBH published article about in [Marcantonio, Enrico; Curti, Claudio; Battistini, Lucia; Sartori, Andrea; Zanardi, Franca] Univ Parma, Dipartimento Sci Alimenti & Farmaco, Parco Area Sci 27A, I-43124 Parma, Italy; [Cardinale, Luana] Univ Hamburg, Dept Chem, Martin Luther King Pl 6, D-20146 Hamburg, Germany; [Pelosi, Giorgio] Univ Parma, Dipartimento Sci Chim Vita & Sostenibilita Ambien, Parco Area Sci 17A, I-43124 Parma, Italy in 2021.0, Cited 42.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
The peculiar versatility of remotely enolizable 6-methyluracil-5-carbaldehydes as useful vinylogous pronucleophiles in direct, asymmetric [4+2] cyclizations with suitable nitroolefins has been demonstrated. Under the strategic exploitation of noncovalent bifunctional organocatalysis, a dearomative remote enolization strategy was implemented, to generate oQDM-type dienolate intermediates that were efficiently and stereoselectively trapped by either aromatic or aliphatic nitroolefins. A series of functionalized, chiral carbocycle-fused uracils embedding three contiguous stereocenters were thus collected in one step in good yields, with generally good levels of enantioselectivity, and complete diastereocontrol. Furthermore, the ability to provide enantiopure products via simple one-cycle recrystallizations and the possibility to further functionalize these scaffolds without losing their chiral integrity were demonstrated.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles