An article A Highly Selective Manganese-Catalyzed Synthesis of Imines under Phosphine-Free Conditions WOS:000507429400028 published article about METAL-LIGAND COOPERATION; TRANSFER HYDROGENATION; BORROWING HYDROGEN; SECONDARY ALCOHOLS; BETA-ALKYLATION; RUTHENIUM; AMINES; DEHYDROGENATION; COMPLEXES; IRON in [Chai, Huining; Tan, Weiqiang] Qingdao Univ Technol, Sch Environm & Municipal Engn, Qingdao 266033, Peoples R China; [Yu, Kun; Liu, Bo] Univ Jinan, Shandong Acad Med Sci, Sch Med & Life Sci, Jinan 250062, Peoples R China; [Yu, Kun; Liu, Bo] Shandong First Med Univ, Inst Mat Med, Jinan 250062, Peoples R China; [Yu, Kun; Liu, Bo] Shandong Acad Med Sci, Jinan 250062, Peoples R China; [Zhang, Guangyao] Qingdao Univ, Coll Text & Clothing, Res Ctr Intelligent & Wearable Technol, Qingdao 266071, Peoples R China in 2020.0, Cited 54.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Safety of Benzyl Alcohol
An efficient and highly selective phosphine-free NN-manganese(I) complex catalyst system was developed for the acceptorless dehydrogenative coupling of alcohols with amines to form imines. The coupling reactions underwent at 3 mol % catalyst loading, and a large range of alcohols and amines with diverse functional groups was applied, including challenging diol and diamine. The target imine products were obtained in good to excellent yields. The present work provides an alternative method to construct highly active nonprecious metal complex catalysts based on phosphine-free ligands.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles