Wang, X; Li, G; Li, XJ; Zhu, DR; Shen, RW in [Wang, Xin; Li, Gang; Li, Xiaojie; Zhu, Dunru; Shen, Ruwei] Nanjing Tech Univ, State Key Lab Mat Oriented Chem Engn, Coll Chem & Chem Engn, Nanjing 210009, Peoples R China published One-pot three-component reaction of p-quinone monoacetals, l-proline and naphthols to afford N-aryl-2-arylpyrrolidines in 2021, Cited 56. Product Details of 150-76-5. The Name is Mequinol. Through research, I have a further understanding and discovery of 150-76-5.
The one-pot three-component reaction of p-quinone monoacetals (or p-quinol ethers), l-proline and naphthols is developed for the synthesis of N-aryl-2-arylpyrrolidines under mild conditions with high chemo- and regioselectivity. The reaction may involve multiple processes including condensation, decarboxylation and demethoxylation for the the generation of N-arylated 3,4-dihydro-2H-pyrrolium followed by controllable capture by naphthols. In the absence of a naphthol, p-quinone monoacetal coupled with l-proline to form a complex dipyrroloquinoline product.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles