Recently I am researching about ASYMMETRIC TRANSFER HYDROGENATION; ENANTIOSELECTIVE TRANSFER HYDROGENATION; NICKEL-COMPLEXES; IRON CATALYSTS; COBALT; RUTHENIUM; REDUCTION; EFFICIENT; LIGANDS; BONDS, Saw an article supported by the Nazarbayev University via NU-ORAU grant [2016023]; Nazarbayev University via FDCRG grant [240919FD3911]. Formula: C7H6O2. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Segizbayev, M; Oztopcu, O; Hayrapetyan, D; Shakhman, D; Lyssenko, KA; Khalimon, AY. The CAS is 100-83-4. Through research, I have a further understanding and discovery of 3-Hydroxybenzaldehyde
The aminophosphinite pincer complex (POCNH)NiBr was found to effectively catalyze the transfer hydrogenation of aldehydes and ketones with 2-propanol and (KOBu)-Bu-t as a base, presenting a rare example of bifunctional nickel transfer hydrogenation catalysts. The transfer hydrogenation of aldehydes and ketones was found to be selective, tolerating a wide range of other functional groups, including those prone to reduction, such as esters, amides, alkenes, pyridines, and nitriles. The reactions were suggested to proceed via the metal-ligand cooperative mechanism with an intermediacy of an amido (POCN)Ni-II species.
About 3-Hydroxybenzaldehyde, If you have any questions, you can contact Segizbayev, M; Oztopcu, O; Hayrapetyan, D; Shakhman, D; Lyssenko, KA; Khalimon, AY or concate me.. Formula: C7H6O2
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles