So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Han, Xue; Shan, Li-Xin; Zhu, Jin-Xin; Zhang, Chang-Sheng; Zhang, Xiao-Ming; Zhang, Fu-Min; Wang, Hong; Tu, Yong-Qiang; Yang, Ming; Zhang, Wen-Shuo researched the compound: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane( cas:132098-59-0 ).Recommanded Product: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane.They published the article 《Copper-Nitrene-Catalyzed Desymmetric Oxaziridination/1,2-Alkyl Rearrangement of 1,3-Diketones toward Bicyclic Lactams》 about this compound( cas:132098-59-0 ) in Angewandte Chemie, International Edition. Keywords: alkyl azido cyclohexane dione copper nitrene catalyst enantioselective oxaziridination; hexahydropyrroloazepine dione preparation; azidoalkyl cyclopentane dione copper nitrene catalyst enantioselective oxaziridination; hexahydroindolizine dione preparation; Schmidt reaction; bicyclic lactams; chiral copper-nitrene; oxaziridination; rearrangement reaction. We’ll tell you more about this compound (cas:132098-59-0).
The novel copper-nitrene-catalyzed desym. oxaziridination reaction of cyclic diketones with alkyl azides and the subsequent rearrangement of the resulting highly active intermediate, which produces a synthetically challenging chiral bicyclic lactam containing a quaternary carbon center were reported. This procedure not only enriches the copper-nitrene-catalyzed asym. reactions, but also provides an alternative strategy to address the inherent challenges of catalytic asym. Schmidt reactions. This unique reaction could inspire the investigation of novel copper-nitrene-catalyzed asym. transformations and their reaction mechanisms.
When you point to this article, it is believed that you are also very interested in this compound(132098-59-0)Recommanded Product: Bis((S)-4-phenyl-4,5-dihydrooxazol-2-yl)methane and due to space limitations, I can only present the most important information.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles