Khoshyan, A; Pourtahmasb, M; Feizpour, F; Jafarpour, M; Rezaeifard, A in [Khoshyan, Ashkan; Pourtahmasb, Mehrdad; Feizpour, Fahimeh; Jafarpour, Maasoumeh; Rezaeifard, Abdolreza] Univ Birjand, Fac Sci, Dept Chem, Catalysis Res Lab, Birjand 97179414, Iran published Aerobic {Mo72V30} nanocluster-catalysed heterogeneous one-pot tandem synthesis of benzimidazoles in 2019, Cited 53. Recommanded Product: 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
A novel heterogeneous one-pot protocol is developed for tandem aerobic synthesis of benzimidazoles through dehydrogenative coupling of primary benzylic alcohols and aromatic diamines co-catalysed by Keplerate-type {Mo72V30} polyoxometalate and N-hydroxyphthalimide (NHPI). The catalytic system also works well for the synthesis of benzimidazoles using benzaldehydes, as commonly used starting materials, in the absence of NHPI. The high activity of the solid nanocluster provides standard conditions avoiding current limitations of oxidation methods including high catalyst loadings. The spectral results and leaching experiments revealed that the nanocapsule preserved its structural integrity after being reused in consecutive runs.
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,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles