HPLC of Formula: C7H8O. In 2019.0 CHEM-US published article about ASYMMETRIC TRANSFER HYDROGENATION; C-H; SELECTIVE HYDROGENATION; IRON CATALYSTS; PRIMARY AMINES; COMPLEXES; LIGAND; (DE)HYDROGENATION; REDUCTION; NITRILES in [Zhong, Rui; Wei, Zeyuan; Zhang, Wei; Liu, Qiang] Tsinghua Univ, Dept Chem, CBMS, Beijing 100084, Peoples R China; [Liu, Shun] Wuyi Univ, Sch Biotechnol & Hlth Sci, Jiangmen 529090, Guangdong, Peoples R China in 2019.0, Cited 60.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.
Homogeneous catalytic hydrogenation of carbonyl groups is a synthetically useful and widely applied organic transformation. Sustainable chemistry goals require replacing conventional noble transition metal catalysts for hydrogenation by earth-abundant base metals. Herein, we report how a practical in situ catalytic system generated by easily available pincer NHC precursors, CoCl2, and a base enabled efficient and high-yielding hydrogenation of a broad range of ketones and aldehydes (over 50 examples and a maximum turnover number [TON] of 2,610). This is the first example of NHC-Co-catalyzed hydrogenation of C=O bonds using flexible pincer NHC ligands consisting of a N-H substructure. Diastereodivergent hydrogenation of substituted cyclohexanone derivatives was also realized by fine-tuning of the steric bulk of pincer NHC ligands. Additionally, a bis(NHCs)-Co complex was successfully isolated and fully characterized, and it exhibits excellent catalytic activity that equals that of the in-situ-formed catalytic system.
HPLC of Formula: C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Zhong, R; Wei, ZY; Zhang, W; Liu, S; Liu, Q or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles