I found the field of Chemistry very interesting. Saw the article Selective functionalisation of aromatic alcohols with supramolecularly regulated gold(i) catalysts published in 2020.0. Formula: C7H8O2, Reprint Addresses Vidal-Ferran, A (corresponding author), Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain.; Vidal-Ferran, A (corresponding author), Univ Barcelona, Dept Inorgan & Organ Chem, Sect Inorgan Chem, Carrer Marti i Franques 1-11, Barcelona 08028, Spain.; Vidal-Ferran, A (corresponding author), ICREA, Pg Lluis Co 23, Barcelona 08010, Spain.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol
Phosphite-based Au(i) catalytic systems containing an array of structurally diverse polyether-based regulation sites were designed and synthesised. These catalysts have been successfully tested in the Au(i)-catalysed C-H functionalisation of phenols and related derivatives with gold-carbenes derived from diazo compounds. Regulation of the steric congestion around the catalytic Au(i) centreviaion-dipole interactions with an external regulation agent led to an enhancement of both the activity and selectivity of the reaction. This new approach in supramolecular gold(i) catalysis has been applied to the derivatisation of an array of substituted phenols and related substrates and to the preparation of an advanced synthetic intermediate of the anticancer agent tamoxifen. The effects of the regulation agent on the selectivity and yield of the reaction have been studied and rationalised using DFT-D calculations.
Formula: C7H8O2. About m-Methoxyphenol, If you have any questions, you can contact Carreras, L; Franconetti, A; Grabulosa, A; Frontera, A; Vidal-Ferran, A or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles