Category: 100-51-6

Authors Afewerki, S; Palo-Nieto, C; Cordova, A in GEORG THIEME VERLAG KG published article about TRANSFER HYDROGENATION; MESOCELLULAR FOAM; SELECTIVE HYDROGENATION; NANOPARTICLES; SILICA; MILD; CARBOCYCLIZATION; DEOXYGENATION; ALDEHYDES; SECONDARY in [Afewerki, Samson; Palo-Nieto, Carlos; Cordova, Armando] Mid Sweden Univ, Dept Nat Sci, Holmgatan 10, S-85170 Sundsvall, Sweden in 2020.0, Cited 45.0. SDS of cas: 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6

An efficient heterogeneous palladium-catalyzed transfer hydrogenolysis of primary, secondary, and tertiary benzylic alcohols using formic acid as hydrogen source has been developed. The resulting hydrocarbon products were obtained in excellent yields. Moreover, the system exhibits high chemoselectivity, reacting only with the hydroxy groups in the presence of other functional groups, and excellent recyclability.

About Benzyl Alcohol, If you have any questions, you can contact Afewerki, S; Palo-Nieto, C; Cordova, A or concate me.. SDS of cas: 100-51-6

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Authors Webb, EW; Park, JB; Cole, EL; Donnelly, DJ; Bonacorsi, SJ; Ewing, WR; Doyle, AG in AMER CHEMICAL SOC published article about ALIPHATIC CARBOXYLIC-ACIDS; DECARBOXYLATIVE FLUORINATION; SYNTHETIC METHODS; QUATERNARY CARBONS; FLUORIDE; ALKENES; DEOXYFLUORINATION; HYDROFLUORINATION; AMINOFLUORINATION; DIFLUORINATION in [Webb, Eric W.; Park, John B.; Doyle, Abigail G.] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA; [Cole, Erin L.; Donnelly, David J.; Bonacorsi, Samuel J.] Bristol Myers Squibb Res & Dev, PET Radiochem Synth, Discovery Chem Platforms, Princeton, NJ 08543 USA; [Ewing, William R.] Bristol Myers Squibb, Discovery Chem, Princeton, NJ 08543 USA in 2020.0, Cited 75.0. Application In Synthesis of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6

We report a redox-neutral method for nucleophilic fluorination of N-hydroxyphthalimide esters using an Ir photocatalyst under visible light irradiation. The method provides access to a broad range of aliphatic fluorides, including primary, secondary, and tertiary benzylic fluorides as well as unactivated tertiary fluorides, that are typically inaccessible by nucleophilic fluorination due to competing elimination. In addition, we show that the decarboxylative fluorination conditions are readily adapted to radiofluorination with [F-18]KF. We propose that the reactions proceed by two electron transfers between the Ir catalyst and redox-active ester substrate to afford a carbocation intermediate that undergoes subsequent trapping by fluoride. Examples of trapping with O- and C-centered nucleophiles and deoxyfluorination via N-hydroxyphthalimidoyl oxalates are also presented, suggesting that this approach may offer a general blueprint for affecting redox-neutral S(N)1 substitutions under mild conditions.

Application In Synthesis of Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Webb, EW; Park, JB; Cole, EL; Donnelly, DJ; Bonacorsi, SJ; Ewing, WR; Doyle, AG or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Surface Grafting Polyphosphoesters on Cellulose Nanocrystals To Improve the Emulsification Efficacy WOS:000484644000024 published article about IN-WATER EMULSIONS; PICKERING EMULSIONS; NANOPARTICLES; PARTICLES; STABILIZATION; PH; MICROPARTICLES; DISPERSIBILITY; EMULSIFIERS; FABRICATION in [Hiranphinyophat, Suphatra] Kansai Univ, Grad Sch Sci & Engn, 3-3-35 Yamate Cho, Suita, Osaka 5640836, Japan; [Iwasaki, Yasuhiko] Kansai Univ, Fac Chem Mat & Bioengn, 3-3-35 Yamate Cho, Suita, Osaka 5640836, Japan; [Iwasaki, Yasuhiko] Kansai Univ, ORDIST, 3-3-35 Yamate Cho, Suita, Osaka 5640836, Japan; [Asaumi, Yuta] Osaka Inst Technol, Grad Sch Engn, Asahi Ku, 5-16-1 Omiya, Osaka 5358585, Japan; [Fujii, Syuji] Osaka Inst Technol, Fac Engn, Asahi Ku, 5-16-1 Omiya, Osaka 5358585, Japan; [Fujii, Syuji] Osaka Inst Technol, Nanomat Microdevices Res Ctr, Asahi Ku, 5-16-1 Omiya, Osaka 5358585, Japan in 2019.0, Cited 66.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Quality Control of Benzyl Alcohol

Particle-stabilized emulsion systems have been developed to address the problematic properties of conventional surfactants. However, the nature and properties of the fine particles used in such systems remain a critical issue for stability enhancement. Herein, we describe a thermoswitchable oil-in-water (O/W) particle-stabilized emulsion that exhibits improved stability due to the addition of cellulose nanocrystals (CNCs) modified with poly[2-isopropoxy-2-oxo-1,3,2-dioxaphospholane] (PIPP), which exhibits relatively good biocompatibility and biodegradability. Various parameters, such as surface activity, concentration of particles, polarity of solvents, and temperatures, on the formation of emulsions with CNCs grafted with PIPP (CNC-g-PIPP) were investigated. Results showed that the surface activity of CNC-g-PIPP was significantly improved compared with the unmodified material. Heptane-in-water particle-stabilized emulsions with CNC-g-PIPP were stably formed, and the effect of temperature on the stability of the emulsions was characterized. CNC-g-PIPP exhibited function as an effective particulate emulsifier at 4 degrees C because of the strong adsorption at the oil-water interface. However, the emulsions rapidly disintegrated at 45 degrees C, which is above the low critical solution temperature of PIPP on CNC, as the hydrophobized CNC-g-PIPP desorbed from the oil-water interface. Based on these findings, a thermally induced reversible emulsification/demulsification was presented. The resulting switchable particle-stabilized emulsion based on CNC-g-PIPP shows promise for the ability to control the stability of an emulsion in response to temperature, which is attractive for use in biological applications.

Quality Control of Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Hiranphinyophat, S; Asaumi, Y; Fujii, S; Iwasaki, Y or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Authors Zhou, SH; Dai, FL; Xiang, ZY; Song, T; Liu, DT; Lu, FC; Qi, HS in ELSEVIER SCIENCE BV published article about CATALYTIC TRANSFER HYDROGENATION; LEWIS-ACID SITES; GAMMA-VALEROLACTONE; HETEROGENEOUS CATALYST; METHYL LEVULINATE; CONVERSION; CELLULOSE; ETHERIFICATION; TRANSFORMATION; MICROSPHERES in [Zhou, Shenghui; Dai, Fanglin; Xiang, Zhouyang; Song, Tao; Liu, Detao; Lu, Fachuang; Qi, Haisong] South China Univ Technol, State Key Lab Pulp & Paper Engn, Guangzhou 510691, Guangdong, Peoples R China; [Lu, Fachuang; Qi, Haisong] Dept Guangdong Engn Res Ctr Green Fine Chem, Guangzhou 510640, Guangdong, Peoples R China in 2019.0, Cited 55.0. SDS of cas: 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6

Both value-added utilization of low-rank renewable feedstocks to prepare catalytic materials and selective transformation of bioderived aldehydes are very attractive topics. Herein, lignosulfonate, a waste by-product from the paper industry, was simply assembled with ZrCl4 under non-toxic hydrothermal conditions for scalable preparation of Zr-containing polyphenolic biopolymer catalysts (Zr-LS). Systematic characterizations indicated that the strong coordination between Zr4+ and phenolic hydroxyl groups in lignosulfonate led to the formation of strong Lewis acid-base couple sites (Zr4+-O2-) and porous inorganic-organic framework structure (mesopores centered at 6.1 nm), while the inherent sulfonic groups in lignosulphonate could serve as Bronsted acidic sites. The cooperative role of these versatile acid-base sites in Zr-LS afforded excellent catalytic performance for Meerwein-Ponndorf-Verley (MPV) reaction of a broad range of bioderived platform chemicals under mild conditions (80 degrees C), especially of furfural (FF) to furfuryl alcohol (FA), in quantitative yields (96%) with high FA formation rate of 9600 mu mol g(-1)h(-1) and TOF of 4.37 h(-1). Kinetic studies revealed that the activation energy of the MPV reduction of FF was as low as 52.25 kJ/mol, accounting for the high reaction rate. Isotopic labelling experiments demonstrated direct hydrogen transfer from the alpha-C of 2-PrOH to the alpha-C of FF on acid-base sites was the rate-determining step. Moreover, Zr-LS showed good recyclability for at least seven reaction cycles.

SDS of cas: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Zhou, SH; Dai, FL; Xiang, ZY; Song, T; Liu, DT; Lu, FC; Qi, HS or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Celik, ZD; Erten, H; Cabaroglu, T in [Celik, Zeynep Dilan] Cukurova Univ, Dept Biotechnol, TR-01330 Adana, Turkey; [Celik, Zeynep Dilan; Erten, Huseyin; Cabaroglu, Turgut] Cukurova Univ, Dept Food Engn, TR-01330 Adana, Turkey published The Influence of Selected Autochthonous Saccharomyces cerevisiae Strains on the Physicochemical and Sensory Properties of Narince Wines in 2019.0, Cited 32.0. Formula: C7H8O. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.

Vitis vinifera cv. Narince is a Turkish native white grape variety. In this study, volatile and sensory properties of Narince wines that are produced with autochthonous Saccharomyces cerevisiae (S. cerevisiae) strains and commercial strain were compared. Autochthonous yeast strains 1044 (MG017575), 1088 (MG017577), and 1281 (MG017581) were previously isolated from spontaneous fermentations of Narince grapes. Volatile compounds formed in wines were extracted using a liquid-liquid extraction method and determined by GC-MS-FID. All yeast strains fermented Narince grape juice to dryness. The differences between the volatile profiles of the yeast strains were determined. Wines fermented with autochthonous strains 1281 and 1044 produced a higher amount of acetates and ethyl esters. While the highest concentrations of ethyl hexanoate and hexyl acetate were found in wine fermented with 1044, the highest concentrations of ethyl octanoate, ethyl decanoate, isoamyl acetate, and 2-phenylethyl acetate were found in wine fermented with strain 1281. Also, the highest contents of 2-phenyl ethanol and linalool were found in wine fermented with strain 1281. According to sensory analysis, the wine fermented with 1281 achieved the best scores in floral and fruity attributes, as well as balance and global impression. The data obtained in the present study showed that autochthonous yeast strains affect the final physicochemical composition and sensory profile of Narince wines.

About Benzyl Alcohol, If you have any questions, you can contact Celik, ZD; Erten, H; Cabaroglu, T or concate me.. Formula: C7H8O

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: 100-51-6. Parker, BF; Hosoya, H; Arnold, J; Tsurugi, H; Mashima, K in [Parker, Bernard F.; Hosoya, Hiromu; Tsurugi, Hayato; Mashima, Kazushi] Osaka Univ, Grad Sch Engn Sci, Dept Chem, Toyonaka, Osaka 5608531, Japan; [Parker, Bernard F.; Arnold, John] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA published alpha-Diimine-Niobium Complex-Catalyzed Deoxychlorination of Benzyl Ethers with Silicon Tetrachloride in 2019, Cited 34. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.

alpha-Diimine niobium complexes serve as catalysts for deoxygenation of benzyl ethers by silicon tetrachloride (SiCl4) to cleanly give two equivalents of the corresponding benzyl chlorides, where SiCl4 has the dual function of oxygen scavenger and chloride source with the formation of a silyl ether or silica as the only byproduct. The reaction mechanism has two successive trans-etherification steps that are mediated by the niobium catalyst, first forming one equivalent of benzyl chloride along with the corresponding silyl ether intermediate that undergoes the same reaction pathway to give the second equivalent of benzyl chloride and silyl ether.

Recommanded Product: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Parker, BF; Hosoya, H; Arnold, J; Tsurugi, H; Mashima, K or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: 100-51-6. Singh, O; Gupta, P; Singh, A; Maji, A; Singh, UP; Ghosh, K in [Singh, Ovender; Gupta, Priyanka; Singh, Anshu; Maji, Ankur; Singh, Udai P.; Ghosh, Kaushik] IIT Roorkee, Dept Chem, Roorkee 247667, Uttar Pradesh, India published Selective oxidation of benzyl alcohol to benzaldehyde, 1-phenylethanol to acetophenone and fluorene to fluorenol catalysed by iron (II) complexes supported by pincer-type ligands: Studies on rapid degradation of organic dyes in 2019.0, Cited 65.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.

Hexacoordinated non-heme iron complexes [Fe-II(L-1)(2)](ClO4)(2) (1) and [Fe-II(L-2)(2)](PF6)(2) (2) have been synthesized using ligands L-1 = (E)-2-chloro-6-(2-(pyridin-2ylmethylene) hydrazinyl)pyridine and L-2 = (E)-2-chloro-6-(2-(1-(pyridin-2-yl)ethylidene)hydrazinyl) pyridine]. These complexes are highly active non-heme iron catalysts to catalyze the C (sp(3))-H bonds of alkanes. These iron complexes have been characterized using ESI-MS analysis and molecular structures were determined by X-ray crystallography. ESI – MS analysis also helped to understand the generation of intermediate species like Fe-III-OOH and Fe-IV=O. DFT and TD-DFT calculations revealed that the oxidation reactions were performed through high-valent iron center and a probable reaction mechanism was proposed. These complexes were also utilized for the degradation of orange II and methylene blue dyes.

Recommanded Product: 100-51-6. About Benzyl Alcohol, If you have any questions, you can contact Singh, O; Gupta, P; Singh, A; Maji, A; Singh, UP; Ghosh, K or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Lin, MMH; Boss, PK; Walker, ME; Sumby, KM; Grbin, PR; Jiranek, V in [Lin, Mandy Man-Hsi; Walker, Michelle E.; Sumby, Krista M.; Grbin, Paul R.; Jiranek, Vladimir] Univ Adelaide, Sch Agr Food & Wine, Dept Wine & Food Sci, Urrbrae, SA, Australia; [Boss, Paul K.] CSIRO, Locked Bag 2, Glen Osmond, SA, Australia; [Boss, Paul K.; Sumby, Krista M.; Grbin, Paul R.; Jiranek, Vladimir] Australian Res Council Training Ctr Innovat Wine, Glen Osmond, SA 5064, Australia published Evaluation of indigenous non-Saccharomyces yeasts isolated from a South Australian vineyard for their potential as wine starter cultures in 2020.0, Cited 60.0. SDS of cas: 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6.

The use of non-Saccharomyces yeast in conjunction with Saccharomyces cerevisiae in wine fermentation is a growing trend in the wine industry. Non-Saccharomyces, through their distinctive production of secondary metabolites, have the potential to positively contribute to wine sensory profile. To discover new candidate strains for development as starter cultures, indigenous non-Saccharomyces were isolated from un-inoculated fermenting Shiraz musts from a South Australian vineyard (McLaren Vale wine region) and characterised. Among the 77 isolates, 7 species belonging to 5 genera (Kazachstartia, Aureobasidium, Meyerozyma, Wickerhamomyces and Torulaspora) were identified by sequencing the internal transcribed spacer regions of the 5.8S rRNA gene (ITS1-5.8S-ITS2 region). The indigenous isolates were evaluated for oenological properties, namely, ethanol tolerance, enzyme activity, and H2S production. To determine their potential industrial use as starter cultures, representative isolates of each species were assessed in a sterile chemically defined grape juice and Viognier grape juice to evaluate their contribution to fermentation kinetics and production of key metabolites, including volatile compounds.

About Benzyl Alcohol, If you have any questions, you can contact Lin, MMH; Boss, PK; Walker, ME; Sumby, KM; Grbin, PR; Jiranek, V or concate me.. SDS of cas: 100-51-6

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recently I am researching about ALIPHATIC POLYESTERS; TRIBLOCK COPOLYMERS; CRYSTALLIZATION KINETICS; ENZYMATIC DEGRADATION; EPSILON-CAPROLACTONE; L-LACTIDE; POLYMERIZATION; MIDBLOCK, Saw an article supported by the . Published in ELSEVIER SCI LTD in OXFORD ,Authors: Zahir, L; Kida, T; Tanaka, R; Nakayama, Y; Shiono, T; Kawasaki, N; Yamano, N; Nakayama, A. The CAS is 100-51-6. Through research, I have a further understanding and discovery of Benzyl Alcohol. COA of Formula: C7H8O

As a promising biodegradable and biorenewable alternative to ubiquitous petrochemical plastics, poly(L-lactide) (PLLA) can be widely employed in biomedical and pharmaceutical fields. In this work, triblock copolymers, poly(L-lactide)-b-poly(2-methyl-1,3-propanediyl adipate)-b-poly(L-lactide) (PLLA-b-PMPA-b-PLLA)s, were synthesized by two-step polymerization from 2-methyl-1,3-propanediol (MP), adipic acid (AA) and L-lactide (LLA) as new biodegradable thermoplastic elastomers. The copolymers exhibited glass-transition temperature at below -40 degrees C and melting temperature at 140-160 degrees C. These copolymers showed much higher elongation at break and lower tensile modulus than those of PLLA. Enzymatic degradation tests of the obtained copolymers were performed using proteinase K and lipase PS as catalysts in hydrolysis reaction to demonstrate rapid degradation for these copolymers. Seawater biodegradability test was conducted for 28 days for each sample. The triblock copolymer and PMPA homopolymer were found to show about 50% biodegradation within 28 days representing very high biodegradable property in sea-water. (C) 2020 The Authors. Published by Elsevier Ltd.

COA of Formula: C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Zahir, L; Kida, T; Tanaka, R; Nakayama, Y; Shiono, T; Kawasaki, N; Yamano, N; Nakayama, A or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Contribution of Pichia manshurica strains to aroma profile of organic wines WOS:000528149300001 published article about VOLATILE PHENOL PRODUCTION; BRETTANOMYCES-BRUXELLENSIS; SPOILAGE YEASTS; SULFUR-DIOXIDE; ESTER FORMATION; VBNC STATE; GUILLIERMONDII; CULTURABILITY; RECLASSIFICATION; MEMBRANIFACIENS in [Perpetuini, Giorgia; Tittarelli, Fabrizia; Battistelli, Noemi; Suzzi, Giovanna; Tofalo, Rosanna] Univ Teramo, Fac BioSci & Technol Food Agr & Environm, Via R Balzarini1, I-64100 Teramo, Italy in 2020.0, Cited 48.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. HPLC of Formula: C7H8O

In this study, the volatile compounds produced by 11 Pichia manshurica strains-isolated from spoiled bottled organic wines of Montepulciano d’Abruzzo and filter membranes-were evaluated in must and wine. Moreover, a quick, reliable and inexpensive method to identify this spoilage species was reported. In particular, a species-specific primer pair was developed using 26S rRNA as target gene. Primers were tested on different yeast species and a band of 300 bp was obtained only for P. manshurica strains. More than 70 volatile compounds were identified. The differences were quantitative rather than qualitative and the majority of the strains released compounds associated with off-flavours and off-odours in must and wine. The obtained data revealed the ability of P. manshurica strains to release compounds which could produce off-flavours and odours.

HPLC of Formula: C7H8O. About Benzyl Alcohol, If you have any questions, you can contact Perpetuini, G; Tittarelli, F; Battistelli, N; Suzzi, G; Tofalo, R or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles