Category: 150-19-6

Authors Fischer, O; Hubert, A; Heinrich, MR in AMER CHEMICAL SOC published article about DEUTERIUM-EXCHANGE; REGIOSELECTIVE DEUTERATION; ANTIOXIDANT ACTIVITY; PEPTIDE-SYNTHESIS; H/D EXCHANGE; INHIBITION; MECHANISM; METHYL; DISSOCIATION; REACTIVITY in [Fischer, Oliver; Hubert, Anja; Heinrich, Markus R.] Friedrich Alexander Univ Erlangen Nurnberg, Dept Chem & Pharm, Pharmaceut Chem, D-91058 Erlangen, Germany in 2020, Cited 65. Name: m-Methoxyphenol. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Taking advantage of the differentiating effect of the solvent methanol, deuterations of electron-rich aromatic systems can be carried out under mild acid catalysis and thus under far milder conditions than known so far. The exceptional functional group tolerance observed under the optimized conditions, which even includes highly acid-labile groups, results from a hitherto unexploited shifted selectivity in protonation, and enabled simple and straightforward access to complex deuterium-labeled compounds.

About m-Methoxyphenol, If you have any questions, you can contact Fischer, O; Hubert, A; Heinrich, MR or concate me.. Category: indole-building-block

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: m-Methoxyphenol. Recently I am researching about ORDERED MESOPOROUS CARBON; NICKEL BORIDE; HYDROGENATION; CONVERSION; OXIDATION; PHENOL; CHEMICALS; BIOMASS; HYDROLYSIS; STRATEGIES, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [NSFC-21776251, 21625604, 21671172]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Zhou, YL; Gao, YJ; Zhong, X; Jiang, WB; Liang, YL; Niu, PF; Li, MC; Zhuang, GL; Li, XN; Wang, JG. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

The development of robust electrocatalysts for electrocatalytic hydrogenation (ECH) of guaiacol and related lignin model monomers is necessary for the stabilization or upgrading of bio-oil. Additionally, the efficiency of biomass conversion to bio-oil products remains below the minimum requirements for its implementation at scale. Herein, a PtNiB/CMK-3 catalyst with pronounced ECH performance in the conversion of guaiacol and related model lignin monomers to bio-oil under optimally mild conditions, through a modulation strategy that modified the electronic structure of PtNi via boron alloying, is prepared. Notably, the optimized PtNiB/CMK-3 exhibited an inspiring high faradaic efficiency of 86.2%, which is significantly higher (13.7 times) than that of the PtNi/CMK-3 without B-doping (6.3%). Experimental results and theoretical calculations showed that the B-doping optimized the PtNiB alloy surface electron structure, simultaneously promoting substrate and intermediate adsorption and the ECH process. In addition, the uniform dispersion of PtNiB nanoparticles embedded within the mesoporous channels of CMK-3 ensures an enhanced utilization efficiency, leading to improvements in stability and bio-oil product generation. The lab-scale ECH experiment of guaiacol also certified the scale-up potential. This work opens a promising avenue to the rational design of advanced and highly efficient electrocatalysts for biomass upgrading.

About m-Methoxyphenol, If you have any questions, you can contact Zhou, YL; Gao, YJ; Zhong, X; Jiang, WB; Liang, YL; Niu, PF; Li, MC; Zhuang, GL; Li, XN; Wang, JG or concate me.. Category: indole-building-block

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recently I am researching about ARYL-ALPHA-DIAZOACETATES; PROPARGYL REARRANGEMENT; INDUSTRIAL PERSPECTIVE; ORTHO-ARYLATION; COUNTER ANIONS; HYDROPHENOXYLATION; CYCLIZATION; ALKYNES; ACTIVATION; B(C6F5)(3), Saw an article supported by the DAADDeutscher Akademischer Austausch Dienst (DAAD)European Commission. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Adak, T; Schulmeister, J; Dietl, MC; Rudolph, M; Rominger, F; Hashmi, ASK. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol. Formula: C7H8O2

A highly chemo- and stereoselective addition of unprotected phenols to haloalkynes was developed. A ligand and counterion controlled process enabled the highly site-selective and chemoselective C-H bond functionalization of phenol derivatives with haloalkynes in moderate to excellent yield at room temperature. The simple availability of the starting materials in combination with the preferred para-C-H functionalization over a competing O-H insertion makes this an attractive protocol. The stereoselectivity of the products depends on the choice of the catalyst. From a synthetic prospective, this method offers an efficient route towards vinyl chlorides, which are valuable precursors for the synthesis of pharmaceutical drugs.

About m-Methoxyphenol, If you have any questions, you can contact Adak, T; Schulmeister, J; Dietl, MC; Rudolph, M; Rominger, F; Hashmi, ASK or concate me.. Name: m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Name: m-Methoxyphenol. Recently I am researching about AEROBIC OXIDATIVE HYDROXYLATION; DEEP EUTECTIC MIXTURE; VISIBLE-LIGHT; HYDROGEN-PEROXIDE; BORONIC ACIDS; PHOTOREDOX CATALYSIS; ORGANIC FRAMEWORK; METAL; FACILE; MILD, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21871067]; Natural Science Foundation of Guangdong ProvinceNational Natural Science Foundation of Guangdong Province [2018A030313038]; Shenzhen Fundamental Research Projects [JCYJ20180306171838187]; Open Project Program of Hubei Key Laboratory of Drug Synthesis and Optimization, Jingchu University of Technology [OPP2015ZD01]; Open Project Program of Beijing National Laboratory for Molecular Sciences [BNLMS201819]; Harbin Institute of Technology (Shenzhen) (Talent Development Starting Fund from Shenzhen Government). Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Fang, YD; Zhao, R; Yao, Y; Liu, Y; Chang, DH; Yao, M; Shi, L. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

A metal-free and base-free Cl3CCN mediated method was developed for the ipso-hydroxylation of aryl boronic acids to their corresponding phenols, which was promoted by a key unstable Lewis adduct intermediate. This transformation has broad functional group tolerance, and late-stage functionalization was successful as well. After simple investigation, two pathways (radical/ionic mechanism) were suggested, and the beneficial action of blue light needs to be further studied.

Name: m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Fang, YD; Zhao, R; Yao, Y; Liu, Y; Chang, DH; Yao, M; Shi, L or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Zhou, MX; He, ED; Zhang, L; Chen, JZ; Zhang, ZF; Liu, YG; Zhang, WB in [Zhou, Muxing; He, Ende; Zhang, Lu; Zhang, Zhenfeng; Liu, Yangang; Zhang, Wanbin] Shanghai Jiao Tong Univ, Shanghai Key Lab Mol Engn Chiral Drugs, Sch Pharm, 800 Dongchuan Rd, Shanghai 200240, Peoples R China; [Chen, Jianzhong; Zhang, Wanbin] Shanghai Jiao Tong Univ, Sch Chem & Chem Engn, 800 Dongchuan Rd, Shanghai 200240, Peoples R China published Development of a new bicyclic imidazole nucleophilic organocatalyst for direct enantioselective C-acylation in 2019, Cited 62. Quality Control of m-Methoxyphenol. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

A novel chiral nucleophilic organocatalyst easily synthesized from simple starting materials bearing a 5,6,7,8-tetrahydroimidazo[1,2-a]pyridine skeleton has been developed and successfully applied in the direct enantioselective C-acylation of 3-substituted benzofuranones. Its catalytic efficiency was shown to be comparable to that of the previously reported chiral 6,7-dihydro-5H-pyrrolo[1,2-a]imidazole catalyst. A wide range of 3,3-disubstituted benzofuranones, possessing a quaternary stereocenter, were synthesized with high yields and enantioselectivities.

About m-Methoxyphenol, If you have any questions, you can contact Zhou, MX; He, ED; Zhang, L; Chen, JZ; Zhang, ZF; Liu, YG; Zhang, WB or concate me.. Safety of m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: m-Methoxyphenol. I found the field of Chemistry very interesting. Saw the article Expanding the Family of Fluorescent Coumarin[4]arenes: Improved Synthesis, pi-Extension, and Characterization published in 2019.0, Reprint Addresses Venkatakrishnan, P (corresponding author), Indian Inst Technol Madras, Dept Chem, Chennai 600036, Tamil Nadu, India.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol.

A novel series of bicyclic fluorescent heterocalixarenes – C-alkyl coumarin[4]arenes – with built-in chirality has been synthesized successfully in excellent yields under well-optimized, improved reaction conditions. Further, structural elaboration (including pi-extension) of coumarin[4]arenes has been demonstrated by using Pd-catalyzed Suzuki and Sonogashira cross-coupling methods. All of these macrocycles are shown to possess averaged C-4-symmetric conformation in solution as opposed to the coumarin[4]arene tetratriflate derivative of C-2 symmetry in the solid state. Finally, the macrocyclic coumarin[4]arenes reveal UV/near-UV absorption and visible blue emission in solution. Such a visible blue luminescence of this macrocycle highlights its potential for sensing, bioimaging, and light-emissive applications.

Recommanded Product: m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Kumar, P; Venkatakrishnan, P or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Authors Han, X; Yang, J; Liu, YY; Ma, JF in ELSEVIER SCI LTD published article about METAL-ORGANIC FRAMEWORKS; MAGNETIC-PROPERTIES; HIGH-SENSITIVITY; SMALL MOLECULES; LANTHANIDE; FLUORESCENT; SENSORS; LIGAND; MOF; COMPLEXES in [Han, Xue; Yang, Jin; Liu, Ying-Ying; Ma, Jian-Fang] Northeast Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China in 2019.0, Cited 36.0. Recommanded Product: m-Methoxyphenol. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Nine coordination polymers, [Tb(HL)(C2H5OH)(2)] (1), [Eu(HL)(C2H5OH)(2)] (2), [Gd(HL)(C2H5OH)(2)] (3), [Sm (HL)(C2H5OH)(2)] (4), [Th(HL)(C2H5OH)(2)]center dot 0.5H(2)O (5), [Cd-3(HL)(2)(DMF)(2)(H2O)(4)]center dot 4DMF (6), [Zn2L(H2O)]center dot DEF (7), [Mn2L(DMF)(H2O)(3)]center dot 2DMF center dot 3H(2)O (8) and [Co-2(HL)(mu(3)-OH)(H2O)(2)]center dot DMF-2.5H(2)O (9) (H4L = 2,8,14,20-tetraethy1-4,10,16,22-tetrakis(4-carboxybenzyl)oxy)-6,12,18,24- tetra-methoxy-resorcin(4]arene) have been synthesized. In compounds 1-6 and 9, H4L is partially deprotonated to generate HL3-, while in 7 and 8, it is completely deprotonated. Compounds 1-5 are isostructural and exhibit one-dimensional (1D) ribbon, and the ribbons are combined together by C-H center dot center dot center dot pi interactions to yield supramolecular layers, respectively. 6 forms a layer, and the layers are combined by hydrogen bonds to create a 3D supramolecular architecture. 7 and 8 demonstrate 3D frameworks. Compound 9 displays a double-stranded ribbon, where C-H center dot center dot center dot pi interactions and hydrogen bonds link adjacent ribbons to produce a supramolecular 3D framework. The luminescent behaviors of 1-7 have been investigated. Compound 1 is highly luminescent and shows sensing ability for acetone and Fe3+ ions.

Recommanded Product: m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Han, X; Yang, J; Liu, YY; Ma, JF or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

I found the field of Chemistry very interesting. Saw the article Visible light-induced mono-bromination of arenes with BrCCl3 published in 2021. Application In Synthesis of m-Methoxyphenol, Reprint Addresses Cheng, XM; Lu, YN; Loh, TP (corresponding author), Nanjing Tech Univ, Inst Adv Synth, Sch Chem & Mol Engn, Jiangsu Natl Synerget Innovat Ctr Adv Mat,Nanjing, Nanjing 211816, Peoples R China.; Loh, TP (corresponding author), Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

A highly efficient and regioselective bromination of electron-rich arenes and heteroarenes using commercially available BrCCl3 as a Br source has been developed. The reaction was performed in air under mild conditions with photocatalyst Ru(bpy)(3)Cl-2 center dot 6H(2)O, avoiding the usage of strong acids and strong oxidants. Mono-brominated products were obtained with medium to excellent yields (up to 94%). This strategy has shown good compatibility and high para-selectivity, which will facilitate the complicated synthesis.

Application In Synthesis of m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Fan, JL; Wei, QC; Zhu, ES; Gao, J; Cheng, XM; Lu, YN; Loh, TP or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Base-promoted selective O-phosphorylation of aryl triflates with P(O)-H compounds WOS:000535722700003 published article about SECONDARY PHOSPHINE OXIDES; CATALYZED PHOSPHORYLATION; DIRECT ESTERIFICATION; ALCOHOLS; ACID; TYROSINE; AMINES; BONDS in [Yang, Jia] Cent South Univ, Coll Chem & Chem Engn, Changsha 410083, Hunan, Peoples R China; Cent South Univ, Hunan Prov Key Lab Efficient & Clean Utilizat Man, Changsha 410083, Hunan, Peoples R China in 2020.0, Cited 37.0. COA of Formula: C7H8O2. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Compared to previous transition metal-catalyzed C-phosphorylation reactions for constructing C-P bonds, in the absence of transition metal catalysts and ligands, a direct O-phosphorylation of aryl triflates selectively occurred with P(O)-H compounds in the presence of a base via the construction of O-P bonds. This transformation proceeds under simple and mild conditions, and provides a new method for the preparation of valuable organophosphoryl compounds from readily available P(O)-H compounds and triflates. (C) 2020 Elsevier Ltd. All rights reserved.

About m-Methoxyphenol, If you have any questions, you can contact Wang, MY; Yang, J; Wang, S; Zhong, H or concate me.. COA of Formula: C7H8O2

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Application In Synthesis of m-Methoxyphenol. In 2019.0 SCI REP-UK published article about IMMUNE RECONSTITUTION; HIV-INFECTION; TUBERCULOSIS; THERAPY; AIDS; ASSOCIATION; INITIATION in [Yen, Yung-Feng] Taipei City Hosp, Sect Infect Dis, Taipei, Taiwan; [Yen, Yung-Feng; Chen, Yi-Ming Arthur] Kaohsiung Med Univ, Ctr Infect Dis & Canc Res, Kaohsiung, Taiwan; [Yen, Yung-Feng; Jen, I. -An; Lin, Su-I.] Natl Yang Ming Univ, Dept & Inst Publ Hlth, Taipei, Taiwan; [Yen, Yung-Feng] Natl Taipei Univ Nursing & Hlth Sci, Dept Hlth Care Management, Taipei, Taiwan; [Chen, Marcelo] Mackay Mem Hosp, Dept Urol, Taipei, Taiwan; [Chen, Marcelo] Mackay Jr Coll Med Nursing & Management, Dept Cosmet Applicat & Management, Taipei, Taiwan; [Chuang, Pei-Hung] Taipei Assoc Hlth & Welf Data Sci, Taipei, Taiwan; [Lee, Chun-Yuan] Kaohsiung Med Univ, Kaohsiung Med Univ Hosp, Dept Internal Med, Div Infect Dis, Kaohsiung, Taiwan; [Lin, Su-I.] Natl Hlth Res Inst, Natl Mosquitoborne Dis Control Res Ctr, Zhunan, Miaoli County, Taiwan; [Chen, Yi-Ming Arthur] Taipei Med Univ, Sch Pharm, Clin Pharmacogen & Pharmacoprote Program, Taipei, Taiwan in 2019.0, Cited 21.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

Highly active antiretroviral therapy (HAART) causes a rapid increase of CD4+T cells counts during the first 3-6 months of treatment and may enhance the development of opportunistic infections (OIs). However, the short- and long-term effects of HAART exposure on the development of incident OIs has not been extensively studied. This nationwide longitudinal study followed up a total of 26,258 people living with HIV/AIDS (PLWHA) to ascertain the short- and long-term effects of HAART on incident OIs. During 150,196 person-years of follow-up, 6,413 (24.4%) PLWHA had new onset of OIs. After adjusting for demographics, comorbidities, and AIDS status, PLWHA who received HAART were more likely to develop OIs than those who did not receive HAART. Considering the short- and long-term effects of HAART on the development of OIs, HAART was found to be a risk factor for developing OIs during the first 90 days of treatment, but a protective factor against OIs after 180 days of HAART use. The risk for the development of active OIs significantly decreased as the duration of HAART increased (P < 0.001). Our study suggests that HAART is a risk factor for developing OIs in the short term, but is a protective factor in the long term. About m-Methoxyphenol, If you have any questions, you can contact Yen, YF; Chen, M; Jen, IA; Chuang, PH; Lee, CY; Lin, SI; Chen, YMA or concate me.. Application In Synthesis of m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles