Category: 150-19-6

Authors Wu, Z; Jiang, H; Zhang, YH in ROYAL SOC CHEMISTRY published article about ARYL BROMIDES; BETA-LACTAMS; HALIDES; BONDS; BENZYLATION; COMBINATION; DERIVATIVES; DESIGN; PHENOL in [Wu, Zhuo; Jiang, Hang; Zhang, Yanghui] Tongji Univ, Shanghai Key Lab Chem Assessment & Sustainabil, Sch Chem Sci & Engn, 1239 Siping Rd, Shanghai 200092, Peoples R China in 2021.0, Cited 77.0. Quality Control of m-Methoxyphenol. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Transition-metal-catalyzed cross-electrophile C(sp(2))-(sp(3)) coupling and C-H alkylation reactions represent two efficient methods for the incorporation of an alkyl group into aromatic rings. Herein, we report a Pd-catalyzed cascade cross-electrophile coupling and C-H alkylation reaction of 2-iodo-alkoxylarenes with alkyl chlorides. Methoxy and benzyloxy groups, which are ubiquitous functional groups and common protecting groups, were utilized as crucial mediators via primary or secondary C(sp(3))-H activation. The reaction provides an innovative and convenient access for the synthesis of alkylated phenol derivatives, which are widely found in bioactive compounds and organic functional materials.

Quality Control of m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Wu, Z; Jiang, H; Zhang, YH or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

I found the field of Chemistry very interesting. Saw the article Machine learning-based prediction of toxicity of organic compounds towards fathead minnow published in 2020. COA of Formula: C7H8O2, Reprint Addresses Chen, XM; Huang, XW; Yu, XL (corresponding author), Hunan Inst Engn, Coll Mat & Chem Engn, Hunan Prov Key Lab Environm Catalysis & Waste Reg, Xiangtan 411104, Hunan, Peoples R China.; Yu, XL (corresponding author), Donghu Rd 18, Xiangtan 411104, Hunan, Peoples R China.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

Predicting the acute toxicity of a large dataset of diverse chemicals against fathead minnows (Pimephales promelas) is challenging. In this paper, 963 organic compounds with acute toxicity towards fathead minnows were split into a training set (482 compounds) and a test set (481 compounds) with an approximate ratio of 1 : 1. Only six molecular descriptors were used to establish the quantitative structure-activity/toxicity relationship (QSAR/QSTR) model for 96 hourpLC(50)through a support vector machine (SVM) along with genetic algorithm. The optimal SVM model (R-2= 0.756) was verified using both internal (leave-one-out cross-validation) and external validations. The validation results (q(int)(2)= 0.699 andq(ext)(2)= 0.744) were satisfactory in predicting acute toxicity in fathead minnows compared with other models reported in the literature, although our SVM model has only six molecular descriptors and a large data set for the test set consisting of 481 compounds.

About m-Methoxyphenol, If you have any questions, you can contact Chen, XM; Dang, LM; Yang, H; Huang, XW; Yu, XL or concate me.. COA of Formula: C7H8O2

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article C-Glycosylation enabled by N-(glycosyloxy)acetamides WOS:000531337600010 published article about STEREOSELECTIVE-SYNTHESIS; STEREOCONTROLLED SYNTHESIS; ARYL GLYCOSIDES; O-GLYCOSIDE; DERIVATIVES; REARRANGEMENT; GLYCALS; STRATEGIES; CATALYST; DESIGN in [Liu, Miao; Li, Tian; Wu, Xia; Liu, Meng; Xiong, De-Cai; Ye, Xin-Shan] Peking Univ, Sch Pharmaceut Sci, State Key Lab Nat & Biomimet Drugs, Beijing 100191, Peoples R China; [Li, Bo-Han] Peking Univ, Sch Basic Med Sci, Inst Syst Biomed, Beijing 100191, Peoples R China in 2020.0, Cited 47.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Safety of m-Methoxyphenol

The C-glycosylation of C-nucleophiles including allyltrimethylsilane, silyl enol ethers and phenols with N-(glycosyloxy)acetamides as glycosyl donors has been realized. This protocol provides a convenient and practical route for the synthesis of alkyl C-glycosides and aryl 2-deoxy-beta-C-glycosides under mild reaction conditions.

About m-Methoxyphenol, If you have any questions, you can contact Liu, M; Li, BH; Li, T; Wu, X; Liu, M; Xiong, DC; Ye, XS or concate me.. Safety of m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Facile and efficient 3-chlorophenol sensor development based on photolumenescent core-shell CdSe/ZnS quantum dots WOS:000562813800023 published article about GLASSY-CARBON ELECTRODE; LIGHT-EMITTING-DIODES; ELECTROCHEMICAL DETERMINATION; PENTACHLOROPHENOL; NANOCRYSTALS; OXIDATION; COMPOSITE; GRAPHENE; FILM; NANOCOMPOSITE in [Rahman, Mohammed M.; Asiri, Abdullah M.] King Abdulaziz Univ, Fac Sci, Ctr Excellence Adv Mat Res CEAMR, Jeddah 21589, Saudi Arabia; [Rahman, Mohammed M.; Asiri, Abdullah M.] King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah 21589, Saudi Arabia; [Karim, Mohammad Rezaul] King Saud Univ, Deanship Sci Res DSR, Ctr Excellence Res Engn Mat CEREM, Riyadh 11421, Saudi Arabia; [Karim, Mohammad Rezaul] KA CARE Energy Res & Innovat Ctr, Riyadh 11421, Saudi Arabia; [Alam, M. M.] Shahjalal Univ Sci & Technol, Dept Chem Engn & Polymer Sci, Sylhet 3100, Bangladesh; [Zaman, M. Badruz] Qual Engn Test Estab, Dept Natl Def, Gatineau, PQ J8X 1C6, Canada; [Alharthi, Nabeel; Alharbi, Hamad] King Saud Univ, Coll Engn, Mech Engn Dept, Riyadh 11421, Saudi Arabia in 2020.0, Cited 84.0. Quality Control of m-Methoxyphenol. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Quantum dots (QDs) are semiconducting inorganic nanoparticles, tiny molecules of 2-10 nm sizes to strength the quantum confinements of electrons. The QDs are good enough to emit light onto electrons for exciting and returning to the ground state. Here, CdSe/ZnS core/shell QDs have been prepared and applied for electrochemical sensor development in this approach. Flat glassy carbon electrode (GCE) was coated with CdSe/ZnS QDs as very thin uniform layer to result of the selective and efficient sensor of 3-CP (3-chlorophenol). The significant analytical parameters were calculated from the calibration plot such as sensitivity (3.6392 mu A mu M-1 cm(-2)) and detection limit (26.09 +/- 1.30 pM) with CdSe/ZnS/GCE sensor probe by electrochemical approach. The calibration curve was fitted with the regression co-efficient r(2) = 0.9906 in the range of 0.1 nM similar to 0.1 mM concentration, which denoted as linear dynamic range (LDR). Besides these, it was performed the reproducibility in short response time and successfully validated the fabricated sensor for 3-CP in the real environmental and extracted samples. It is introduced as a noble route to detect the environmental phenolic contaminants using CdSe/ZnS QDs modified sensor by electrochemical method for the safety of healthcare and environmental fields at broad scales.

About m-Methoxyphenol, If you have any questions, you can contact Rahman, MM; Karim, MR; Alam, MM; Zaman, MB; Alharthi, N; Alharbi, H; Asiri, AM or concate me.. Quality Control of m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Name: m-Methoxyphenol. I found the field of Chemistry very interesting. Saw the article Aerobic photooxidative hydroxylation of boronic acids catalyzed by anthraquinone-containing polymeric photosensitizer published in 2020, Reprint Addresses Hu, JH (corresponding author), Fudan Univ, Dept Macromol Sci, State Key Lab Mol Engn Polymers, 2005 Songhu Rd, Shanghai 200438, Peoples R China.; Ding, AS (corresponding author), Fudan Univ, Dept Chem, 2005 Songhu Rd, Shanghai 200438, Peoples R China.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol.

We report herein the synthesis of a polymeric photosensitizer and its application in aerobic photooxidative hydroxylation of boronic acids. The polymeric photosensitizer was synthesized by the condensation of anthraquinone-2-carbonyl chloride (AQ-2-COCl) with poly (2-hydroxyethyl methacrylate) (PHEMA). The photo-oxidative hydroxylation of boronic acids using anthraquinone-containing-poly (2-hydroxyethyl methacrylate) (AQ-PHEMA) was then explored and shown to exhibit high efficiency and broad scope. Moreover, AQ-PHEMA could be easily recovered and reused for more than 20 times without significant loss of the catalytic activity.

About m-Methoxyphenol, If you have any questions, you can contact Chen, Y; Hu, JH; Ding, AS or concate me.. Name: m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recently I am researching about BENCHMARK THERMODYNAMIC PROPERTIES; THERMOPHYSICAL PROPERTIES; VAPOR-PRESSURES; VAPORIZATION; ENTHALPIES; HEAT; CALORIMETRY; COMBUSTION, Saw an article supported by the Government of the Russian Federation [220, 14, Z50.31.0038]; German Science Foundation (DFG)German Research Foundation (DFG) [SPP 1708, VE 265-14/2]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Verevkin, SP; Konnova, ME; Turovtsev, VV; Riabchunova, AV; Pimerzin, AA. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol. Recommanded Product: 150-19-6

The methoxy-, hydroxy-, and carbonyl-substituted benzenes are the simplest fragments from the lignin separation feedstocks. Extensive experimental thermochemical studies of these compounds were carried out, including combustion calorimetry, vapor pressure measurements, and differential scanning calorimetry. We have collected available primary experimental results on enthalpies of formation and vapor pressures as well as on phase transitions, liquid-gas, liquid-solid, and crystal-liquid. These data were evaluated using empirical, semiempirical, and quantum chemical methods. The consistent sets of evaluated thermodynamic data were used to design the method for predicting enthalpies of vaporization and enthalpies of formation of di- and trisubstituted benzenes. It is expected that parameters and pairwise interactions will be transferable to predict the thermochemical properties of poly methoxy-substituted and poly hydroxysubstituted benzenes that appear in reaction products of lignin transformations in the value-adding chemicals and materials.

Recommanded Product: 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Verevkin, SP; Konnova, ME; Turovtsev, VV; Riabchunova, AV; Pimerzin, AA or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: 150-19-6. Authors Jiao, LY; Ning, ZH; Yin, XM; Hong, Q; Liu, SS; Ma, XX in ELSEVIER published article about in [Jiao, Lin-Yu; Ning, Zi-Hui; Yin, Xiao-Mei; Hong, Qian; Ma, Xiao-Xun] Northwest Univ, Sch Chem Engn, Xian 710069, Shaanxi, Peoples R China; [Jiao, Lin-Yu; Ning, Zi-Hui; Yin, Xiao-Mei; Hong, Qian; Ma, Xiao-Xun] Northwest Univ, Collaborat Innovat Ctr Dev Energy & Chem Ind Nort, Shaanxi Res Ctr Engn Technol Clean Coal Convers,I, Minist Educ Adv Use Technol Shanbei Energy,Chem E, Xian 710069, Shaanxi, Peoples R China; [Liu, Shanshan] Shaanxi Univ Sci & Technol, Coll Chem & Chem Engn, Shaanxi Key Lab Chem Addit Ind, Xian 710021, Shaanxi, Peoples R China in 2021.0, Cited 34.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

An efficient and convenient rhodium(III)-catalyzed chelation-assisted ortho-selective carbon-hydrogen bond alkylation of phenols treated with readily available diazocarbonyl compounds as the alkyl source has been described. Migratory carbene insertion represents the principal step to realize this carbenoid coupling transformation, giving rise to a broad rang of alkylated products and at the same time, releasing nitrogen gas as sole byproduct. This protocol offers exclusive regioselectivities, moderate to excellent chemical yields, and good functional group tolerance.

About m-Methoxyphenol, If you have any questions, you can contact Jiao, LY; Ning, ZH; Yin, XM; Hong, Q; Liu, SS; Ma, XX or concate me.. Recommanded Product: 150-19-6

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article An insight into the OPAHs and SPAHs formation mechanisms during alkaline lignin pyrolysis at different temperatures WOS:000663088900002 published article about STEAM GASIFICATION; BIOMASS PYROLYSIS; INHERENT ALKALI; CANCER-RISK; FLY-ASH; BIO-OIL; PAHS; BEHAVIORS; EVOLUTION; GAS in [Xiao, Lingfeng; Hu, Song; Han, Hengda; Ren, Qiangqiang; He, Limo; Jiang, Long; Su, Sheng; Wang, Yi; Xiang, Jun] Huazhong Univ Sci & Technol, Sch Energy & Power Engn, State Key Lab Coal Combust, Wuhan 430074, Peoples R China; [Hu, Song; Su, Sheng; Xiang, Jun] Huazhong Univ Sci & Technol, China EU Inst Clean & Renewable Energy, Wuhan 430074, Peoples R China; [Jiang, Long] Huazhong Univ Sci & Technol, Sch Energy & Power Engn, Dept New Energy Sci & Engn, Wuhan 430074, Peoples R China in 2021, Cited 38. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Recommanded Product: 150-19-6

OPAHs and SPAHs are highly genotoxic and would largely be formed during the thermal conversion of lignin. Herein, the distribution of OPAHs and SPAHs in lignin pyrolytic tar at different temperatures is elaborated with ESI (-) FT-ICR MS and GC-MS, and the formation routes of two typical OPAH and SPAH are deeply explored via DFT. It is found that most of oxygen-containing compounds convert to phenols and their homologues such as guaiacol (a typical precursor of OPAHs) with the temperature increased. The tar prepared at high temperature contains disulfide, thiophene and thiophene homologues, which are typical precursors of SPAHs. FT-ICR-MS strongly suggests that molecular mass of OPAHs and SPAHs compounds mainly concentrates between 200 Da and 400 Da with carbon atom number from 5 to 25 and DBE from 4 to 15. Higher temperature significantly promotes deoxygenation reaction since weighted average carbon atom number and DBE of molecules increase 28.4 % and 12.9 %, while the corresponding weighted average oxygen atom number decreases from 7.21 to 5.96 with temperature rising from 500 degrees C to 900 degrees C. Incorporating with DFT calculation, the pathways of OPAHs and SPAHs during lignin pyrolysis at high temperature are concluded: Guaiacol converts to 1-methoxynaphthalene via 4 methylation reactions, and butene firstly generates thiophene and then converts to methyl-benzothiophene. Among the reactions above, benzene ring and thiophene ring generation steps possess the highest energy barriers (436.74 kJ/mol and 446.33 kJ/mol), further illustrating higher temperature promotes the formation of OPAHs and SPAHs.

Recommanded Product: 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Xiao, LF; Hu, S; Han, HD; Ren, QQ; He, LM; Jiang, L; Su, S; Wang, Y; Xiang, J or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Wang, ZL; Zu, LS in [Wang, Zhonglei; Zu, Liansuo] Tsinghua Univ, Ctr Biol Struct, Beijing Frontier Res,Sch Pharmaceut Sci, Key Lab Bioorgan Phosphorus Chem & Chem Biol,Mini, Beijing 100084, Peoples R China published Organocatalytic enantioselective direct alkylation of phloroglucinol derivatives: asymmetric total synthesis of (+)-aflatoxin B-2 in 2019.0, Cited 56.0. Recommanded Product: 150-19-6. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

The organocatalytic enantioselective Friedel-Crafts alkylation of phloroglucinol derivatives with enals is reported, providing general access to the benzylic chiral centers shown in a variety of phloroglucinol natural products. The synthetic utility is demonstrated by the very concise asymmetric total synthesis of aflatoxins B-2.

Recommanded Product: 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Wang, ZL; Zu, LS or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Product Details of 150-19-6. In 2019.0 J ELECTROANAL CHEM published article about ELECTROCHEMICAL DETECTION; ASCORBIC-ACID; URIC-ACID; DOPAMINE; ELECTRODE; NANOCOMPOSITE; HYDROQUINONE; COMPOSITES; REDUCTION; CATECHOL in [Alam, Mohammad K.; Khan, Feroz A.] Bangladesh Univ Engn & Technol, Dept Phys, Dhaka 1000, Bangladesh; [Rahman, Md Mahbubur] Konkuk Univ, Dept Energy & Mat, Chungju 27478, South Korea; [Rahman, Mohammed M.; Asiri, Abdullah M.] King Abdulaziz Univ, CEAMR, Chem Dept, POB 80203, Jeddah 21589, Saudi Arabia; [Kim, Dojin] Chungnam Natl Univ, Dept Mat Sci & Engn, Daejeon 305764, South Korea in 2019.0, Cited 44.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

This research demonstrated the development of graphene oxide (GO)-gold nanocrystals (AuNCs) compositemodified glassy carbon electrode (GCE) for the sensitive detection of dopamine (DA), uric acid (UA), and 4-aminophenol (4-AP). The GO was synthesized by modified Hummer’s method, which was utilized to prepare GO-AuNCs composites by in situ synthesis method using sodium L(-) malate as a reducing agent. Morphological, X-ray diffraction, and spectral analysis revealed the homogeneous formation of AuNCs with high crystallinity and purity on the GO surface and the sizes of the NCs were decreased with increasing the concentrations of sodium L (-) malate. The optimal GCE/GO-AuNCs sensor exhibited excellent electrocatalytic activity towards the oxidation of DA, UA, and 4-AP. The sensor showed interference-free and selective detection of DA and UA with sensitivities of ca. 30.3 and 17.28 mu A/cm(2)/mu M, respectively, and detection limits of ca. 28 and 50 nM, respectively, with wider dynamic ranges, measured by differential pulse voltammetry (DPV) technique. Whereas, it displayed a sensitivity and detection limit of ca. 5.70 mu A/cm(2)/mu M and 0.017 nM, respectively, for the detection of 4-AP, using current density (J)-voltage (V) measurement method. The sensor also revealed excellent stability, reproducibility, and recoveries of DA, UA, and 4-AP in real samples.

Product Details of 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Alam, MK; Rahman, MM; Rahman, MM; Kim, D; Asiri, AM; Khan, FA or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles