Category: 150-19-6

Carreras, L; Franconetti, A; Grabulosa, A; Frontera, A; Vidal-Ferran, A in [Carreras, Lucas; Vidal-Ferran, Anton] Inst Chem Res Catalonia ICIQ, Av Paisos Catalans 16, Tarragona 43007, Spain; [Franconetti, Antonio; Frontera, Antonio] Univ Illes Balears, Dept Quim, Crta Valldemossa Km 7-5, Palma De Mallorca 07122, Spain; [Grabulosa, Arnald; Vidal-Ferran, Anton] Univ Barcelona, Dept Inorgan & Organ Chem, Sect Inorgan Chem, Carrer Marti i Franques 1-11, Barcelona 08028, Spain; [Vidal-Ferran, Anton] ICREA, Pg Lluis Co 23, Barcelona 08010, Spain published Selective functionalisation of aromatic alcohols with supramolecularly regulated gold(i) catalysts in 2020.0, Cited 64.0. Formula: C7H8O2. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

Phosphite-based Au(i) catalytic systems containing an array of structurally diverse polyether-based regulation sites were designed and synthesised. These catalysts have been successfully tested in the Au(i)-catalysed C-H functionalisation of phenols and related derivatives with gold-carbenes derived from diazo compounds. Regulation of the steric congestion around the catalytic Au(i) centreviaion-dipole interactions with an external regulation agent led to an enhancement of both the activity and selectivity of the reaction. This new approach in supramolecular gold(i) catalysis has been applied to the derivatisation of an array of substituted phenols and related substrates and to the preparation of an advanced synthetic intermediate of the anticancer agent tamoxifen. The effects of the regulation agent on the selectivity and yield of the reaction have been studied and rationalised using DFT-D calculations.

About m-Methoxyphenol, If you have any questions, you can contact Carreras, L; Franconetti, A; Grabulosa, A; Frontera, A; Vidal-Ferran, A or concate me.. Formula: C7H8O2

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recently I am researching about CYCLIC PEPTIDE INHIBITORS; CANCER CELL-GROWTH; DEMETHYLASE 1; POLYAMINE OXIDASE; ANALOGS; TRANYLCYPROMINE; REEXPRESSION; INACTIVATOR; DERIVATIVES, Saw an article supported by the National Institutes of HealthUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USA [1 RO1 CA149095, 1 RO1 CA204345]; Samuel Waxman Cancer Research Foundation; NATIONAL CANCER INSTITUTEUnited States Department of Health & Human ServicesNational Institutes of Health (NIH) – USANIH National Cancer Institute (NCI) [R01CA204345] Funding Source: NIH RePORTER. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Holshouser, S; Dunworth, M; Murray-Stewart, T; Peterson, YK; Burger, P; Kirkpatrick, J; Chen, HH; Casero, RA; Woster, PM. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol. Quality Control of m-Methoxyphenol

We have previously described the synthesis and evaluation of 3,5-diamino-1,2,4-triazole analogues as inhibitors of the flavin-dependent histone demethylase LSD1. These compounds are potent inhibitors of LSD1 without activity against monoamine oxidases A and B, and promote the elevation of H3K4me2 levels in tumor cells in vitro. We now report that the cytotoxicity of these analogues in pancreatic tumor cells correlates with the overexpression of LSD1 in each tumor type. In addition, we show that a subset of these 3,5-diamino-1,2,4-triazole analogues inhibit a related flavin-dependent oxidase, the polyamine catabolic enzyme spermine oxidase (SMOX) in vitro.

About m-Methoxyphenol, If you have any questions, you can contact Holshouser, S; Dunworth, M; Murray-Stewart, T; Peterson, YK; Burger, P; Kirkpatrick, J; Chen, HH; Casero, RA; Woster, PM or concate me.. Quality Control of m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Deng, XL; Zheng, WN; Jin, C; Bai, LY in [Deng, Xile; Zheng, Wenna; Jin, Can; Bai, Lianyang] Hunan Acad Agr Sci, Hunan Agr Biotechnol Res Inst, Key Lab Biol & Control Weeds, Changsha 410125, Peoples R China published Synthesis of Novel 6-Aryloxy-4-chloro-2-phenylpyrimidines as Fungicides and Herbicide Safeners in 2020, Cited 68. HPLC of Formula: C7H8O2. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

Fenclorim is a commercial herbicide safener with fungicidal activity used for chloroacetanilide herbicides, which might be suitable as a lead compound for screening novel fungicides. However, little has been reported so far on the structure-activity relationship of fungicidal activities of fenclorim or its analogues. Here, a series of 4-chloro-6-substituted phenoxy-2-phenylpyrimidine derivatives was synthesized by a substructure splicing route using fenclorim as a lead compound. The structures of synthesized derivatives were characterized by H-1 NMR, C-13 NMR, and HRMS. Their fungicidal and herbicide safening activities were then evaluated. The results revealed that compound 11 had the best fungicidal activity against Sclerotinia sclerotiorum and Thanatephorus cucumeris, which was better than that of the control pyrimethanil. Moreover, compounds 3, 5, and 25 exhibited excellent safening activities against fresh weight, plant height, and root length, respectively. Such activities were significantly improved when compared to fenclorim. In summary, these findings look promising for the preparation of new fungicides and herbicide safeners based on the structure of fenclorim.

About m-Methoxyphenol, If you have any questions, you can contact Deng, XL; Zheng, WN; Jin, C; Bai, LY or concate me.. HPLC of Formula: C7H8O2

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Category: indole-building-block. In 2020.0 CHEM COMMUN published article about ORTHO-ARYLATION; ACTIVATION; GENERATION in [Homma, Yuki; Fukuda, Kazuishi; Iwasawa, Nobuharu; Takaya, Jun] Tokyo Inst Technol, Dept Chem, Meguro Ku, Tokyo 1528551, Japan; [Takaya, Jun] PRESTO, JST, Kawaguchi, Saitama 3320012, Japan in 2020.0, Cited 31.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

Efficient synthesis ofo-borylphenols is achieved through the Ru-catalyzed regio- and site-selective sp(2)C-H borylation of aryl diphenylphosphinites followed by removal of the phosphorus directing group. A successful application to aryl phosphites enables practical one-pot borylation of phenols, demonstrating high synthetic utility of this protocol.

About m-Methoxyphenol, If you have any questions, you can contact Homma, Y; Fukuda, K; Iwasawa, N; Takaya, J or concate me.. Category: indole-building-block

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

I found the field of Chemistry; Science & Technology – Other Topics; Engineering very interesting. Saw the article Extraction of Furfural and Furfural/5-Hydroxymethylfurfural from Mixed Lignocellulosic Biomass-Derived Feedstocks published in 2021.0. COA of Formula: C7H8O2, Reprint Addresses Vlachos, DG (corresponding author), Univ Delaware, Dept Chem & Biomol Engn, Newark, DE 19716 USA.; Vlachos, DG (corresponding author), Univ Delaware, RAPID Mfg Inst, Catalysis Ctr Energy Innovat, Newark, DE 19716 USA.; Vlachos, DG (corresponding author), Univ Delaware, Delaware Energy Inst DEI, Newark, DE 19716 USA.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

We present a combined in silico and experimental study on the extraction of furfural and 5-hydroxymethylfurfural (HMF) in aqueous-organic biphasic systems. We predict the liquid-liquid equilibria and furfural/HMF partition coefficients of over 2200 water-organic biphasic systems using the multiscale COSMO-RS model and measure experimentally single-component (furfural) and mixture (furfural and HMF) partition coefficients at room and dehydration reaction-relevant temperatures in 28 solvents. We find the experimental data to be within a factor of 2 from the COSMO-RS predictions. Even though furfural and HMF have chemical similarity, the slight differences in molecular structure render the separation of furfural easier by the supply of more solvents of higher partition coefficient for extraction. We leverage this molecular difference and experimentally demonstrate that with an additional extraction step, using dichloromethane or toluene, we can selectively extract furfural from furfural-HMF mixtures, which can coexist in lignocellulosic biomass dehydration products, despite their partition coefficients being generally correlated. We complement solvent selection criteria for biphasic lignocellulosic biomass processes with a simple mass balance extraction model for determining volume ratios in multistage extraction. Finally, the molecular nature of the preferential furfural extraction is rationalized using COSMO-RS sigma-profile analysis.

About m-Methoxyphenol, If you have any questions, you can contact Wang, ZX; Bhattacharyya, S; Vlachos, DG or concate me.. COA of Formula: C7H8O2

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

In 2020 ACS OMEGA published article about BENZYNE-CLICK CHEMISTRY; FACILE N-ARYLATION; O-ARYLATION; NUCLEOPHILIC-SUBSTITUTION; SELECTIVE SYNTHESIS; GENERATION; EFFICIENT; PHENOLS; MAGNESIUM; REAGENTS in [Muraca, Ana Carolina A.; Raminelli, Cristiano] Univ Fed Sao Paulo, Inst Ciencias Ambientais Quim & Farmaceut, BR-09972270 Diadema, Brazil in 2020, Cited 107. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Computed Properties of C7H8O2

A class of aryne precursors, that is, 2-(trimethylsilyl)aryl 4-chlorobenzenesulfonates, has been developed through well-established synthetic routes, which allow the formation of arynes under relatively mild conditions. All the aryne precursors were obtained from phenols and 4-chlorobenzenesulfonyl chloride, an inexpensive and easy-to-handle reagent with relatively low toxicity, and subjected to nucleophilic addition reactions, providing addition products in yields of 24 to 92%, and to cycloaddition reactions, affording cycloadducts in yields up to 80%. This work provides interesting insights into the mechanisms of aryne generation. In addition, 2-(trimethylsilyl)phenyl 4-chlorobenzenesulfonate was successfully employed in the total synthesis of (+/-)-aporphine.

Computed Properties of C7H8O2. About m-Methoxyphenol, If you have any questions, you can contact Muraca, ACA; Raminelli, C or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recently I am researching about O-H INSERTION; N-H; ALPHA,BETA-UNSATURATED DIAZOKETONES; ARYLATION REACTIONS; ORGANIC-SYNTHESIS; UREA; ENOLDIAZOACETAMIDES; PLATFORMS; PHENOLS, Saw an article supported by the FAPESP (Research Supporting Foundation of the State of Sao Paulo)Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2017/233299, 2015/22003-7, 2019/05002-8]; CNPqConselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPQ) [303437/2015-4]; FAPESPFundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) [2013/50228-8, 2009/54040-8]. SDS of cas: 150-19-6. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Gallo, RDC; Momo, PB; Day, DP; Burtoloso, ACB. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

The catalytic protonation of aryl diazoacetates by strong Bronsted acids, followed by a Friedel-Crafts alkylation reaction with electron rich aromatic compounds, is reported. The reaction provided in a direct fashion 24 geminal diarylacetates in yields of <= 92%. SDS of cas: 150-19-6. About m-Methoxyphenol, If you have any questions, you can contact Gallo, RDC; Momo, PB; Day, DP; Burtoloso, ACB or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Category: indole-building-block. Recently I am researching about WORKS-OF-ART; THERMALLY ASSISTED HYDROLYSIS; ARCHAEOLOGICAL WOOD; MUSICAL-INSTRUMENTS; GC-MS; METHYLATION; VARNISHES; PROPOLIS; INSIGHTS; PHENOLS, Saw an article supported by the . Published in ELSEVIER in AMSTERDAM ,Authors: Kasprzok, L; Fabbri, D; Rombola, AG; Rovetta, T; Malagodi, M. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

Historical stringed musical instruments are a unique class of cultural heritage objects. Crafted during the 16th-18th centuries, these instruments remain somewhat mysterious. Due to the absence of written historical documents of traditional varnish recipes, their chemical characterization is the only way to recover the lost ‘secret’ of the Cremonese stringed instrument maker Antonio Stradivari and his contemporaries, whose traditions had been lost by 1800. Pyrolysis combined with gas chromatography-mass spectrometry (GC-MS) using solid-phase microextraction (SPME) followed by on-fiber silylation (Py SPME Syl GC-MS) was applied to a large collection of standards to evaluate its validity for compositional analysis and material identification of historical stringed instrument varnishes. The standards included pure resins (colophony, amber, mastic, sandarac, elemi), different types of shellac, as well as colorants or additives such as madder, dragon’s blood, and Aloe vera powder, and other materials (propolis, beeswax). The aim was to obtain an extensive collection of GC-MS data of silylated pyrolysis products useful for the characterization of the finishes of these unique historical objects. A set of distinct pyrolysis patterns and products were chosen as specific molecular markers for each standard. The method was applied to instrument varnish samples from Stainer, Baioni, Amati, Guarneri, Gasparo da Salo, Maggini, and Guadagnini instruments. The method was shown to be effective for the identification of oxidized lignin, drying oils, and diterpenic resins. In the case of dragon’s blood, madder, shellac, and propolis new markers were identified, suggesting their presence in some instrument varnishes. The identification of proteins and madder appeared most challenging.

Category: indole-building-block. About m-Methoxyphenol, If you have any questions, you can contact Kasprzok, L; Fabbri, D; Rombola, AG; Rovetta, T; Malagodi, M or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

COA of Formula: C7H8O2. I found the field of Chemistry very interesting. Saw the article ARS-TiO2 photocatalyzed direct functionalization of sp2 C-H bonds toward thiocyanation and cyclization reactions under visible light published in 2020.0, Reprint Addresses Hosseini-Sarvari, M (corresponding author), Shiraz Univ, Dept Chem, Shiraz 7194684795, Iran.. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol.

An ARS-TiO2 photocatalyst has been prepared, by a simple method through stirring a mixture of ARS and TiO2 at room temperature in the dark, to extend the photocatalytic response of titanium dioxide toward the visible light spectrum. The synergic effect of ARS and TiO2 in the photocatalyst system has catalyzed direct C-H functionalization of sp2 C-H bonds toward thiocyanation and cyclization reactions. Several aromatic and heteroaromatic scaffolds (2-phenylamino-thiazole, phenol, aniline, indole and pyrrole derivatives) were treated with the thiocyanate anion at room temperature. Herein, the first report on thiocyanation of phenol and synthesis of 2-aminobenzothiazole derivatives under visible light is presented.

COA of Formula: C7H8O2. About m-Methoxyphenol, If you have any questions, you can contact Koohgard, M; Hosseinpour, Z; Sarvestani, AM; Hosseini-Sarvari, M or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article A simple, direct synthesis of 3-vinylindoles from the carbocation-catalysed dehydrative cross-coupling of ketones and indoles. A combined experimental and computational study WOS:000456353200005 published article about SUBSTITUTED CARBAZOLES; ORGANOBORON REAGENTS; DENSITY FUNCTIONALS; PRACTICAL SYNTHESIS; ACID; ALKYLATION; EFFICIENT; HYDROARYLATION; SOLVATION; CHLORIDE in [Barbero, Margherita; Dughera, Stefano; Alberti, Sara; Ghigo, Giovanni] Univ Torino, Dipartimento Chim, Via P Giuria 7, I-10125 Turin, Italy in 2019.0, Cited 84.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Computed Properties of C7H8O2

A straightforward synthesis of a library of largely new 3-vinylindoles via a clean dehydrative coupling reaction between ketones and indoles has been developed. Highly stable, non-nucleophilic aryl(2-methylindol-3-yl)methylium salts have been used as efficient Lewis acid catalysts. The advantages of the reaction are the use of equimolar amounts of inexpensive and easily available reagents, the low catalyst amount, high atom efficiency, the production of only one molecule of water as a by-product and the mild reaction conditions. Computational studies of two specific reaction mechanism instances show that both steric and electronic effects heavily influence the nature of the final products, whether a methyl group in position 2 of the indole is present or absent. (C) 2018 Elsevier Ltd. All rights reserved.

About m-Methoxyphenol, If you have any questions, you can contact Barbero, M; Dughera, S; Alberti, S; Ghigo, G or concate me.. Computed Properties of C7H8O2

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles