Category: 150-19-6

An article Selective hydrogenolysis of lignin-derived aryl ethers over Co/C@N catalysts WOS:000510524900061 published article about METAL-ORGANIC FRAMEWORK; HYDRODEOXYGENATION; BIOMASS; COBALT; EFFICIENT; SPECTRA; BONDS; CYCLOHEXANOLS; CONVERSION; REDUCTION in [Song, Qing-Lu; Zhao, Yun-Peng; Wu, Fa-Peng; Li, Guo-Sheng; Fan, Xing; Cao, Jing-Pei; Wei, Xian-Yong] China Univ Min & Technol, Minist Educ, Key Lab Coal Proc & Efficient Utilizat, Xuzhou 221116, Jiangsu, Peoples R China; [Zhao, Yun-Peng] Taiyuan Univ Technol, Minist Sci & Technol, Training Base, State Key Lab Coal Sci & Technol Jointly Construc, Taiyuan 030024, Peoples R China; [Wang, Rui-Yu] China Univ Min & Technol, Low Carbon Energy Inst, Xuzhou 221008, Jiangsu, Peoples R China in 2020.0, Cited 50.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Quality Control of m-Methoxyphenol

Low aromaticity and a large number of oxygen-bridged bonds among the aromatic structural units of lignin make it possible to obtain chemicals directly. A novel Co/C@N catalyst with high activity towards hydrogenolysis of lignin-derived aryl ethers was synthesized according to the pyrolysis process of a predesigned ZIF-67. According to the results of characterization by powder X-ray diffraction (XRD), N-2 adsorption-desorption, scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS), Co was reduced by the carbonized organic linker of ZIF-67, and N was doped into the carbon skeleton of the catalyst. The effects of holding time, temperature, and initial H-2 pressure on the catalytic performance of Co/C@N were evaluated in the selective hydrogenolysis of benzyl phenyl ether (BPE). BPE was completely converted and the selectivity of monomer reached to 98.2% under optimized reaction conditions. The C-alk-O bond in BPE was first dissociated to form toluene and phenol, and then phenol was rapidly hydrogenated to form cyclohexanol. Furthermore, the Co/C@N catalyst shows high activity for hydroprocessing and selective cleavage of other lignin-derived aryl ethers, including phenylethyl phenyl, diphenyl ether, dibenzyl ether, dinaphthalene ether, guaiacol, anisole and veratrole. (C) 2019 Elsevier Ltd. All rights reserved.

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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

An article Catalytic depolymerization of calcium lignosulfonate by NiMgFeOx derived from sub-micron sized NiMgFe hydrotalcite prepared by introducing hydroxyl compounds WOS:000496717900022 published article about LIGNIN DEPOLYMERIZATION; EFFICIENT; CHLORIDE in [Han, Hongjing; Li, Jinxin; Wang, Haiying; Chen, Yanguang; Zhang, Yanan; Wang, Yizhen; Zhang, Mei] Northeast Petr Univ, Sch Chem & Chem Engn, Daqing 163318, Peoples R China; [Han, Hongjing; Li, Jinxin; Wang, Haiying; Chen, Yanguang; Zhang, Yanan; Wang, Yizhen; Zhang, Mei] Heilongjiang Prov Key Lab Oil & Gas Chem Technol, Daqing 163318, Peoples R China; [Xue, Feng] Shandong Sinocera Funct Mat Co Ltd, Dongying 257000, Peoples R China in 2019.0, Cited 23.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6. Category: indole-building-block

A new method for regulating the synthesis of NiMgFe hydrotalcites (NMF LDHs) with the addition of hydroxyl compounds was proposed. A series of NMF LDHs were prepared by the above method, and then were calcined to obtain the NiMgFeOx (NMFOx) samples. The NMFOx samples were characterized by XRD, SEM, TG-DTG, XPS and CO2 -TPD, respectively. The catalytic performance of NMFOx for depolymerizing calcium lignosulfonate (CLS) was evaluated by hydrothermal reaction. The results showed that the addition of hydroxyl compounds favored reducing the particle sizes of NMF LDHs. For the depolymerization of CSL, the yield of liquid product increased from 45% to 75.8% with the addition of NMFOx-ethanol (NMFOx-ET). The liquid products were mainly phenolics, aromatics, ketones and esters. The total selectivity of oxy-containing compounds was over 90.6%, among them, the phenolics were approximately 35.2%. The valence of Ni and Fe, crystalline phase and basicity almost remained unchanged. The NMFOx-ET samples were recycled for the depolymerization of CLS, moreover, the NMFOx-ET samples had high activity and stability after 4 cycles. (C) 2019 The Chemical Industry and Engineering Society of China, and Chemical Industry Press Co., Ltd. All rights reserved.

Bye, fridends, I hope you can learn more about C7H8O2, If you have any questions, you can browse other blog as well. See you lster.. Category: indole-building-block

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Quality Control of m-Methoxyphenol. Authors Fereidoonnezhad, M; Tabaei, SMH; Sakhteman, A; Seradj, H; Faghih, Z; Faghih, Z; Mojaddami, A; Sadeghian, B; Rezaei, Z in ELSEVIER published article about in [Fereidoonnezhad, Masood; Mojaddami, Ayyub] Ahvaz Jundishapur Univ Med Sci, Sch Pharm, Dept Med Chem, Ahvaz, Iran; [Fereidoonnezhad, Masood; Tabaei, S. Mohammad Hossein; Sakhteman, Amirhossein; Seradj, Hassan; Faghih, Zeinab; Mojaddami, Ayyub; Sadeghian, Batool; Rezaei, Zahra] Shiraz Univ Med Sci, Dept Med Chem, Sch Pharm, Shiraz, Iran; [Fereidoonnezhad, Masood; Tabaei, S. Mohammad Hossein; Sakhteman, Amirhossein; Seradj, Hassan; Faghih, Zeinab; Mojaddami, Ayyub; Sadeghian, Batool; Rezaei, Zahra] Shiraz Univ Med Sci, Pharmaceut Sci Res Ctr, Sch Pharm, Shiraz, Iran; [Faghih, Zahra] Shiraz Univ Med Sci, Sch Med, Shiraz Inst Canc Res, Shiraz, Iran in 2020, Cited 38. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Dichloroacetate (DCA) as a mitochondria-targeting small molecule, through inhibition of pyruvate dehydrogenase kinases (PDK1-4), promotes mitochondria-regulated apoptosis and hence, inhibits tumour growth and reduces its proliferation. In this study, a series of novel N-aryl-2,2-dichloroacetamide and aryl-2,2-dichloroacetate derivatives were designed and synthesized. Their cytotoxic activities against various human cancer cell lines including A549, HCA-7, MCF-7, MDA-MB-231, KB and SKOV3 were evaluated. These compounds showed satisfactory potencies with much higher anticancer activity than the parent compound DCA, against the studied cancer cell lines. Molecular docking studies were also done to find their binding site and types of their interactions with PDKs isoenzymes. Among the synthesized compounds, 2,2-dichloro-N-(9,10-dioxo-9,10-dihydroanthracen-1-yl)acetamide (f1) can also induce A549 cells apoptosis. Therefore, compound f1 might have a potential value for further study in drug development. QSAR studies of this class of compounds were also explored using a collection of chemometrics methods. (C) 2020 Published by Elsevier B.V.

Quality Control of m-Methoxyphenol. About m-Methoxyphenol, If you have any questions, you can contact Fereidoonnezhad, M; Tabaei, SMH; Sakhteman, A; Seradj, H; Faghih, Z; Faghih, Z; Mojaddami, A; Sadeghian, B; Rezaei, Z or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Recommanded Product: 150-19-6. Authors Kawamoto, Y; Kobayashi, T; Ito, H in AMER CHEMICAL SOC published article about in [Kawamoto, Yuichiro; Kobayashi, Toyoharu; Ito, Hisanaka] Tokyo Univ Pharm & Life Sci, Sch Life Sci, Tokyo 1920392, Japan in 2021.0, Cited 22.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Stachyodin A, possessing a unique spirotetrahydrofuran ring system, was isolated from the roots of Indigofera stachyodes in 2018. The first total synthesis of racemic stachyodin A was accomplished in 14 steps. The efficient stereoselective synthetic route involved one-pot Suzuki coupling and stereocontrolled epoxidation followed by reductive opening and spirocyclization.

Welcome to talk about 150-19-6, If you have any questions, you can contact Kawamoto, Y; Kobayashi, T; Ito, H or send Email.. Recommanded Product: 150-19-6

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Product Details of 150-19-6. In 2020.0 ORG LETT published article about STEREOSELECTIVE P-O; ORTHO-LITHIATION; BIS(DIMETHYLAMINO)PHOSPHORYL GROUP; CARBONYL-COMPOUNDS; FACILE SYNTHESIS; C REARRANGEMENT; MIGRATION; PHENOLS; OLEFINS; ROUTES in [Alessi, Manlio; Patel, Jignesh J.; Zumbansen, Kristina; Snieckus, Victor] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada in 2020.0, Cited 58.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

We report on the tetraethylphosphorodiamidate (-OP(O)(NEt2)(2)) group as an effective directed metalation group (DMG). Lithiation-electrophile quench of 1 provides a general synthesis of ortho-substituted aryl and naphthyl phosphorodiamidates 4-8. We also describe the phospha anionic ortho-Fries (AoF) rearrangement of the phosphorodiamidates 1a,1b -> 2 or 3 and its vinylogous counterpart to the ortho-tolyl phosphorodiamidates 5b -> 13. Intermolecular competition experiments demonstrate the approximately equal DMG strength of the -OP(O)(NEt2)(2) and the most powerful OCONEt2 groups.

Product Details of 150-19-6. Bye, fridends, I hope you can learn more about C7H8O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Formula: C7H8O2. Authors Song, CY; Nie, JQ; Ma, C; Lu, CF; Wang, FY; Yang, GC in ELSEVIER published article about in [Song, Chaoyang; Nie, Junqi; Ma, Chao; Lu, Cuifen; Wang, Feiyi; Yang, Guichun] Hubei Univ, Coll Chem & Chem Engn, Hubei Collaborat Innovat Ctr Adv Organ Chem Mat, Minist Educ Key Lab Synth & Applicat Organ Funct, Wuhan 430062, Peoples R China in 2021, Cited 71. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

1,2,3-Triazole contained conjugated porous polymers (CPPs) have recently emerged as a new class of efficient photocatalysts. To gain more insight into the excellent photocatalytic activity of this kind of CPPs, herein, we report the design and preparation of a series of 1,2,3-triazole-based CPPs via oxidative coupling polymerization to study their photocatalytic performance. These CPPs have donor-acceptor properties and 1,2,3-triazole serves as an electron acceptor. The resulting CPPs with thiophene, carbazole and diphenylamine as electron donor units, respectively, have distinct porosities and optoelectronic properties, and showed effective photocatalytic performance towards oxidative hydroxylation of arylboric acids and alkylation of vinylarenes with diethyl bromomalonate or bromoacetonitrile. The thiophene contained CPP was a more efficient photocatalyst for the catalytic reactions, which can be attributed to its smaller optical band gap and greater charge separation effi-ciency. Furthermore, PTPT has shown reliable recyclability with no significant loss in its catalytic activity.

Formula: C7H8O2. Bye, fridends, I hope you can learn more about C7H8O2, If you have any questions, you can browse other blog as well. See you lster.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Name: m-Methoxyphenol. Recently I am researching about VITRO ANTITUMOR-ACTIVITY; BIOLOGICAL EVALUATION; QUINOXALINE DERIVATIVES; FACILE SYNTHESIS; AGENTS; CONDENSATION; HETEROCYCLES; FLUORESCENCE; QUINAZOLINE; SENSITIZERS, Saw an article supported by the SERBDepartment of Science & Technology (India)Science Engineering Research Board (SERB), India [PDF/2016/001813]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Das, S; Maity, S; Ghosh, P; Paul, BK; Dutta, A. The CAS is 150-19-6. Through research, I have a further understanding and discovery of m-Methoxyphenol

Synthesis of fluorescent molecules has drawn considerable attention due to their potential applications in life and material sciences. Here we report a metal-free approach to a new class of fluorophore, namely, 6-(2-hydroxyarypisoindolo[2,1-a]quinoxalin-11(5H)-ones exploiting ninhydrin ring system via base promoted tandem cyclization. The readily obtainable phenolic adducts of ninhydrin undergoes smooth reaction with o-phenylenediamine in refluxing ethylene glycol/Et3N via breaking of C-C bond, N-insertion, followed by heterocyclization to furnish the fully unsaturated isoindoloquinoxaline framework. Structures of the products are in good agreement with their IR, 1HNMR, (CNMR)-C-13, and mass spectral data. The photophysical properties of the synthesized compounds were studied by UV-vis absorption and fluorescence spectroscopic techniques under ambient conditions, and the results reveal an interesting property of large Stokes shift.

Welcome to talk about 150-19-6, If you have any questions, you can contact Das, S; Maity, S; Ghosh, P; Paul, BK; Dutta, A or send Email.. Name: m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Safety of m-Methoxyphenol. In 2020.0 CHEM COMMUN published article about GOLD-CATALYZED CYCLOISOMERIZATION; CYCLIZATION; ENYNES; ISOMERIZATION; LIGANDS; ALKOXYCYCLIZATION; CARBOCYCLIZATION; COMPLEXES in [Han, Xu; Retailleau, Pascal; Voituriez, Arnaud] Univ Paris Saclay, CNRS, Inst Chim Subst Nat, UPR 2301, F-91198 Gif Sur Yvette, France; [Han, Xu; Gandon, Vincent] Univ Paris Saclay, CNRS, Inst Chim Mol & Mat Orsay, F-91405 Orsay, France; [Gandon, Vincent] Inst Polytech Paris, Lab Chim Mol LCM, CNRS UMR 9168, Ecole Polytech, Route Saclay, F-91128 Palaiseau, France in 2020.0, Cited 57.0. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

An enantioselective Au(i)-catalyzed cyclization/nucleophilic addition process is developed, starting from 1,5-enyne substrates. A broad scope of O-, N- and C-nucleophiles was introduced in order to provide the corresponding chiral cyclopentene derivatives in moderate to high yields and up to 96 : 4 enantiomeric ratio.

Welcome to talk about 150-19-6, If you have any questions, you can contact Han, X; Retailleau, P; Gandon, V; Voituriez, A or send Email.. Safety of m-Methoxyphenol

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Authors Yen, YF; Chen, M; Jen, IA; Chuang, PH; Lee, CY; Lin, SI; Chen, YMA in NATURE PUBLISHING GROUP published article about IMMUNE RECONSTITUTION; HIV-INFECTION; TUBERCULOSIS; THERAPY; AIDS; ASSOCIATION; INITIATION in [Yen, Yung-Feng] Taipei City Hosp, Sect Infect Dis, Taipei, Taiwan; [Yen, Yung-Feng; Chen, Yi-Ming Arthur] Kaohsiung Med Univ, Ctr Infect Dis & Canc Res, Kaohsiung, Taiwan; [Yen, Yung-Feng; Jen, I. -An; Lin, Su-I.] Natl Yang Ming Univ, Dept & Inst Publ Hlth, Taipei, Taiwan; [Yen, Yung-Feng] Natl Taipei Univ Nursing & Hlth Sci, Dept Hlth Care Management, Taipei, Taiwan; [Chen, Marcelo] Mackay Mem Hosp, Dept Urol, Taipei, Taiwan; [Chen, Marcelo] Mackay Jr Coll Med Nursing & Management, Dept Cosmet Applicat & Management, Taipei, Taiwan; [Chuang, Pei-Hung] Taipei Assoc Hlth & Welf Data Sci, Taipei, Taiwan; [Lee, Chun-Yuan] Kaohsiung Med Univ, Kaohsiung Med Univ Hosp, Dept Internal Med, Div Infect Dis, Kaohsiung, Taiwan; [Lin, Su-I.] Natl Hlth Res Inst, Natl Mosquitoborne Dis Control Res Ctr, Zhunan, Miaoli County, Taiwan; [Chen, Yi-Ming Arthur] Taipei Med Univ, Sch Pharm, Clin Pharmacogen & Pharmacoprote Program, Taipei, Taiwan in 2019.0, Cited 21.0. Category: indole-building-block. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6

Highly active antiretroviral therapy (HAART) causes a rapid increase of CD4+T cells counts during the first 3-6 months of treatment and may enhance the development of opportunistic infections (OIs). However, the short- and long-term effects of HAART exposure on the development of incident OIs has not been extensively studied. This nationwide longitudinal study followed up a total of 26,258 people living with HIV/AIDS (PLWHA) to ascertain the short- and long-term effects of HAART on incident OIs. During 150,196 person-years of follow-up, 6,413 (24.4%) PLWHA had new onset of OIs. After adjusting for demographics, comorbidities, and AIDS status, PLWHA who received HAART were more likely to develop OIs than those who did not receive HAART. Considering the short- and long-term effects of HAART on the development of OIs, HAART was found to be a risk factor for developing OIs during the first 90 days of treatment, but a protective factor against OIs after 180 days of HAART use. The risk for the development of active OIs significantly decreased as the duration of HAART increased (P < 0.001). Our study suggests that HAART is a risk factor for developing OIs in the short term, but is a protective factor in the long term. Welcome to talk about 150-19-6, If you have any questions, you can contact Yen, YF; Chen, M; Jen, IA; Chuang, PH; Lee, CY; Lin, SI; Chen, YMA or send Email.. Category: indole-building-block

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles

Herrera-Vazquez, FS; Matadamas-Martinez, F; Aguayo-Ortiz, R; Dominguez, L; Ramirez-Apan, T; Yepez-Mulia, L; Hernandez-Luis, F in [Herrera-Vazquez, Frida S.; Matadamas-Martinez, Felix; Hernandez-Luis, Francisco] Univ Nacl Autonoma Mexico, Dept Farm, Mexico City 04510, DF, Mexico; [Matadamas-Martinez, Felix; Yepez-Mulia, Lilian] Inst Mexicano Seguro Social, Ctr Med Nacl Siglo XXI, Unidad Med Alta Especialidad, Hosp Pediat, Mexico City 06720, DF, Mexico; [Aguayo-Ortiz, Rodrigo; Dominguez, Laura] Univ Nacl Autonoma Mexico, Dept Fisicoquim, Mexico City 04510, DF, Mexico; [Aguayo-Ortiz, Rodrigo] Univ Michigan, Dept Internal Med, Div Cardiovasc Med, Ann Arbor, MI 48109 USA; [Ramirez-Apan, Teresa] Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico published Design, Synthesis and Evaluation of 2,4-Diaminoquinazoline Derivatives as Potential Tubulin Polymerization Inhibitors in 2020, Cited 56. Computed Properties of C7H8O2. The Name is m-Methoxyphenol. Through research, I have a further understanding and discovery of 150-19-6.

Microtubules are highly dynamic polymers composed of alpha- and beta-tubulin proteins that have been shown to be potential therapeutic targets for the development of anticancer drugs. Currently, a wide variety of chemically diverse agents that bind to beta-tubulin have been reported. Nocodazole (NZ) and colchicine (COL) are well-known tubulin-depolymerizing agents that have close binding sites in the beta-tubulin. In this study, we designed and synthesized a set of nine 2,4-diaminoquinazoline derivatives that could occupy both NZ and COL binding sites. The synthesized compounds were evaluated for their antiproliferative activities against five cancer cell lines (PC-3, HCT-15, MCF-7, MDA-MB-231, and SK-LU-1), a noncancerous one (COS-7), and peripheral blood mononuclear cells (PBMC). The effect of compounds4 eand4 ion tubulin organization and polymerization was analyzed on the SK-LU-1 cell line by indirect immunofluorescence, western blotting, and tubulin polymerization assays. Our results demonstrated that both compounds exert their antiproliferative activity by inhibiting tubulin polymerization. Finally, a possible binding pose of4 iin the NZ/COL binding site was determined by using molecular docking and molecular dynamics (MD) approaches. To our knowledge, this is the first report of non-N-substituted 2,4-diaminoquinazoline derivatives with the ability to inhibit tubulin polymerization.

Computed Properties of C7H8O2. About m-Methoxyphenol, If you have any questions, you can contact Herrera-Vazquez, FS; Matadamas-Martinez, F; Aguayo-Ortiz, R; Dominguez, L; Ramirez-Apan, T; Yepez-Mulia, L; Hernandez-Luis, F or concate me.

Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles