An article [(PPh3)(2)NiCl2]-Catalyzed C-N Bond Formation Reaction via Borrowing Hydrogen Strategy: Access to Diverse Secondary Amines and Quinolines WOS:000649101400087 published article about ALKYLATED AMINES; EFFICIENT; ALCOHOLS; KETONES; DEHYDROGENATION; ACTIVATION; COMPLEXES; CATALYSIS in [Donthireddy, S. N. R.; Pandey, Vipin K.; Rit, Arnab] Indian Inst Technol Madras, Dept Chem, Chennai 600036, Tamil Nadu, India in 2021, Cited 57. Safety of Benzyl Alcohol. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Commercially available [(PPh3)(2)NiCl2] was found to be an efficient catalyst for the mono-N-alkylation of (hetero)aromatic amines, employing alcohols to deliver diverse secondary amines, including the drug intermediates chloropyramine (5b) and mepyramine (5c), in excellent yields (up to 97%) via the borrowing hydrogen strategy. This method shows a superior activity (TON up to 10000) with a broad substrate scope at a low catalyst loading of 1 mol % and a short reaction time. Further, this strategy is also successful in accessing various quinoline derivatives following the acceptorless dehydrogenation pathway.
Safety of Benzyl Alcohol. About Benzyl Alcohol, If you have any questions, you can contact Donthireddy, SNR; Pandey, VK; Rit, A or concate me.
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles