Recommanded Product: 1008-89-5. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: 2-Phenylpyridine, is researched, Molecular C11H9N, CAS is 1008-89-5, about Bromide-Promoted Visible-Light-Induced Reductive Minisci Reaction with Aldehydes. Author is Wang, Zhongzhen; Liu, Qiong; Ji, Xiaochen; Deng, Guo-Jun; Huang, Huawen.
Radical addition is a robust tool for bond formation. While ketyl radical reactivity of aldehydes by photoredox has been well-established, herein, a pathway for umpolung addition of aldehydes with or without external reductant is revealed. Hence, the reductive alkylations and challenging benzylations of nitrogen heteroarenes (i.e., Minisci reactions) are enabled by the bromide-promoted visible light-mediated photocatalysis. The present protocol offers a mild, viable method for late-stage alkylations and transition-metal-free benzylations of biol. active nitrogen-heteroarene mols. Mechanistic studies are indicative of a bromide-initiated acyl radical mechanism in the absence of external reductant.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles