An article Organoselenium-catalyzed enantioselective syn-dichlorination of unbiased alkenes WOS:000481562300005 published article about ASYMMETRIC ADDITION-REACTIONS; CIS-CHLORINATION; CHIRAL DISELENIDES; OLEFINS; DIHALOGENATION; METHOXYSELENENYLATION; ELECTROPHILES; HALOGENATION; CHLORIDES; REGIO in [Gilbert, Bradley B.; Eey, Stanley T-C; Ryabchuk, Pavel; Garry, Olivia; Denmark, Scott E.] Univ Illinois, Dept Chem, 245 Roger Adams Lab,Box 18,600 S Mathews Ave, Urbana, IL 61801 USA in 2019.0, Cited 61.0. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6. Application In Synthesis of Benzyl Alcohol
The enantioselective dichlorination of alkenes is a continuing challenge in organic synthesis owing to the limitations of selective and independent antarafacial delivery of both electrophilic chlorenium and nucleophilic chloride to an olefin. Development of a general method for the enantioselective dichlorination of isolated alkenes would allow access to a wide variety of polyhalogenated natural products. Accordingly, the enantioselective suprafacial dichlorination of alkenes catalyzed by electrophilic organoselenium reagents has been developed to address these limitations. The evaluation of twenty-three diselenides as precatalysts for enantioselective dichlorination is described, with a maximum e.r. of 76:24 Additionally, mechanistic studies suggest an unexpected Dynamic Kinetic Asymmetric Transformation (DyKAT) process may be operative. (C) 2019 Elsevier Ltd. All rights reserved.
Bye, fridends, I hope you can learn more about C7H8O, If you have any questions, you can browse other blog as well. See you lster.. Application In Synthesis of Benzyl Alcohol
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles