Authors Vielhaber, T; Faust, K; Topf, C in AMER CHEMICAL SOC published article about MOLYBDENUM; CHROMIUM; NITRILES in [Vielhaber, Thomas; Faust, Kirill; Topf, Christoph] Johannes Kepler Univ JKU, Inst Catalysis INCA, A-4040 Linz, Austria in 2020.0, Cited 34.0. Category: indole-building-block. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
We report on the preparation of a series of phosphorusnitrogen donor ligand complexes [M(CO)(4)(PN)], where M = Cr, Mo, W and PN is 2-(diphenylphosphino)-ethylamine. The organometallic compounds were readily obtained upon reacting the respective metal hexacarbonyls with equimolar amounts of the pertinent ligand in the presence of tetraethylammonium bromide. The PN-ligated metal carbonyls were fully characterized by standard spectroscopic techniques and X-ray crystallography. The ability of the title compounds to function as homogeneous hydrogenation catalysts was probed in the reduction of acetophenone and benzaldehyde derivatives to yield the corresponding alcohols. The reaction setup was easily assembled by simply combining the components in the autoclave on the bench outside an inert-gas-operated glovebox system
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles