Quality Control of 4-Methoxybenzaldehyde. Authors Jolly, CS; Kochanowski, E; Dodd, CJ; Post, SJ; Hill, HM; Turlington, M in AMER CHEMICAL SOC published article about in [Jolly, Charles S.; Kochanowski, Emma; Dodd, Cayden J.; Post, Savannah J.; Hill, Harrison M.; Turlington, Mark] Berry Coll, Dept Chem & Biochem, Mt Berry, GA 30149 USA in 2021.0, Cited 22.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5
The stereoselective synthesis of terminal bromosubstituted propargylamines via in situ generation of lithium bromoacetylide from 1,2-dibromoethene and addition to Ellman chiral N-tert-butanesulfinyl aldimines is reported. Modest to good yields (43-85%) and diastereoselectivity (dr = 3:1 to >20:1) were achieved for a range of aryl, heteroaryl, alkyl, and alpha,beta-unsaturated substrates. Terminal bromo-substituted propargylamines prepared via this method can be directly used in the frequently employed Cadiot-Chodkiewicz coupling to produce functionalized diynes. The method reported here increases the structural diversity of chiral terminal bromo-substituted propargylamines that can be readily synthesized as previous methods for the stereoselective synthesis of these compounds rely on amino acid precursors from the chiral pool.
Quality Control of 4-Methoxybenzaldehyde. About 4-Methoxybenzaldehyde, If you have any questions, you can contact Jolly, CS; Kochanowski, E; Dodd, CJ; Post, SJ; Hill, HM; Turlington, M or concate me.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles