An article Siloxyaluminate and Siloxygallate Complexes as Models for Framework and Partially Hydrolyzed Framework Sites in Zeolites and Zeotypes WOS:000595228100001 published article about PONNDORF-VERLEY REDUCTION; THERMOLYTIC MOLECULAR PRECURSOR; LEWIS-ACID SITES; SN-BETA ZEOLITES; TRIS(TERT-BUTOXY)SILOXY COMPLEXES; EXTRAFRAMEWORK ALUMINUM; HETEROGENEOUS CATALYSIS; CARBONYL-COMPOUNDS; CRYSTAL-STRUCTURES; BRONSTED ACIDITY in [Dombrowski, James P.; Ziegler, Micah S.; Witzke, Ryan J.; Tilley, T. Don] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA; [Dombrowski, James P.; Ziegler, Micah S.; Levine, Daniel S.; Witzke, Ryan J.; Head-Gordon, Martin; Bell, Alexis T.; Tilley, T. Don] Lawrence Berkeley Natl Lab, Chem Sci Div, 1 Cyclotron Rd, Berkeley, CA 94720 USA; [Phadke, Neelay M.; Mansoor, Erum; Bell, Alexis T.] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA; [Mansoor, Erum; Levine, Daniel S.; Head-Gordon, Martin] Univ Calif Berkeley, Kenneth S Pitzer Ctr Theoret Chem, Dept Chem, Berkeley, CA 94720 USA in 2021.0, Cited 124.0. Product Details of 100-51-6. The Name is Benzyl Alcohol. Through research, I have a further understanding and discovery of 100-51-6
Anionic molecular models for nonhydrolyzed and partially hydrolyzed aluminum and gallium framework sites on silica, M[OSi(OtBu)(3)](4)(-) and HOM[OSi(OtBu)(3)](3)(-) (where M=Al or Ga), were synthesized from anionic chlorides Li{M[OSi(OtBu)(3)](3)Cl} in salt metathesis reactions. Sequestration of lithium cations with [12]crown-4 afforded charge-separated ion pairs composed of monomeric anions M[OSi(OtBu)(3)](4)(-) with outer-sphere [([12]crown-4)(2)Li](+) cations, and hydroxides {HOM[OSi(OtBu)(3)](3)} with pendant [([12]crown-4)Li](+) cations. These molecular models were characterized by single-crystal X-ray diffraction, vibrational spectroscopy, mass spectrometry and NMR spectroscopy. Upon treatment of monomeric [([12]crown-4)Li]{HOM[OSi(OtBu)(3)](3)} complexes with benzyl alcohol, benzyloxide complexes were formed, modeling a possible pathway for the formation of active sites for Meerwin-Ponndorf-Verley (MPV) transfer hydrogenations with Al/Ga-doped silica catalysts.
About Benzyl Alcohol, If you have any questions, you can contact Dombrowski, JP; Ziegler, MS; Phadke, NM; Mansoor, E; Levine, DS; Witzke, RJ; Head-Gordon, M; Bell, AT; Tilley, TD or concate me.. Product Details of 100-51-6
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Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles