Computed Properties of C8H8O2. Wicker, G; Schoch, R; Paradies, J in [Wicker, Garrit; Schoch, Roland; Paradies, Jan] Paderborn Univ, Chem Dept, D-33098 Paderborn, Germany published Diastereoselective Synthesis of Dihydro-quinolin-4-ones by a Borane-Catalyzed Redox-Neutral endo-1,7-Hydride Shift in 2021.0, Cited 68.0. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5.
The borane-catalyzed synthesis of dihydroquinoline-4-ones is developed. The amino-substituted chalcones undergo a 1,7-hydride shift upon Lewis acid activation to form a zwitterionic iminium enolate, which collapses to the dihydroquinoline-4-one scaffold. The reaction proceeds in high yields (75-99%) with an excellent diastereoselectivity of up to >99:1 (cis:trans). The reaction mechanism is investigated by kinetic, isotope labeling, and computational experiments.
Computed Properties of C8H8O2. Welcome to talk about 123-11-5, If you have any questions, you can contact Wicker, G; Schoch, R; Paradies, J or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles