The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. 41354-29-4, Name is Cyproheptadine Hydrochloride Sesquihydrate, SMILES is CN1CC/C(CC1)=C2C3=CC=CC=C3C=CC4=CC=CC=C/24.[H]Cl.[H]Cl.[H]O[H].[H]O[H].[H]O[H].CN5CC/C(CC5)=C6C7=CC=CC=C7C=CC8=CC=CC=C/68, in an article , author is Jiang, Guangbin, once mentioned of 41354-29-4, Category: indole-building-block.
Palladium-catalyzed sequential acylation/annulation of indoles with acyl chlorides using primary amine as the directing group
An attractive and convenient strategy for the direct acylation/annulation of indoles has been developed using Pd(0) as an efficient catalyst. The main feature of this protocol is the use of acyl chlorides as the acylating agents with the primary amine as the directing group. A variety of indolo[1,2-a]quinoxalines were readily obtained in reasonable efficiency and satisfactory yields with good functional group tolerance. Based on control experiments, a tentative catalytic mechanism was proposed.
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Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles