SDS of cas: 123-11-5. In 2021 NEW J CHEM published article about CROSS-COUPLING REACTIONS; DIARYL KETONE SYNTHESIS; ONE-POT SYNTHESIS; ARYLBORONIC ACIDS; ASYMMETRIC 1,4-ADDITION; PALLADIUM(II) COMPLEXES; PLATINUM(II) COMPLEXES; ORGANOBORONIC ACIDS; ALDEHYDES; RHODIUM in [Castillo-Garcia, Antonio A.; Hernandez-Ortega, Simon; Toscano, Ruben A.; Morales-Morales, David] Univ Nacl Autonoma Mexico, Inst Quim, Ciudad Univ, Ciudad De Mexico 04510, Mexico; [Gonzalez-Sebastian, Lucero; Lomas-Romero, Leticia] Univ Autonoma Metropolitana Iztapalapa, Dept Quim, Av San Rafael Atlixco 186, Ciudad De Mexico 09340, Mexico in 2021, Cited 73. The Name is 4-Methoxybenzaldehyde. Through research, I have a further understanding and discovery of 123-11-5.
The synthesis of four novel non-symmetric Ni(ii)-POCOP pincer complexes meta-functionalized with either benzothiazole or benzimidazole at the central aryl ring is described. All complexes were fully characterised in solution by various analytical techniques and the molecular structures in the solid state of complexes 1b, 2a and 2b were unequivocally determined by single crystal X-ray diffraction analysis. In addition, the Ni(ii)-POCOP pincer complexes were efficiently used as catalysts in the synthesis of diarylketones by cross-coupling reactions of functionalized benzaldehydes and boronic acid derivatives under relatively mild conditions. An important aspect of this transformation is the dependence on the steric properties of the donor groups (OPR2) of the pincer ligands, the more active compounds having the phosphinitos bearing isopropyl groups (1a and 2a) than those containing tert-butyl substituents (1b and 2b).
SDS of cas: 123-11-5. Welcome to talk about 123-11-5, If you have any questions, you can contact Castillo-Garcia, AA; Gonzalez-Sebastian, L; Lomas-Romero, L; Hernandez-Ortega, S; Toscano, RA; Morales-Morales, D or send Email.
Reference:
Indole alkaloid derivatives as building blocks of natural products from Bacillus thuringiensis and Bacillus velezensis and their antibacterial and antifungal activity study,
,Preparation of Indole Containing Building Blocks for the Regiospecific Construction of Indole Appended Pyrazoles and Pyrroles